周期性dithioether功能化trifenylamine连接体及其机械反应Cu (I) 协调聚合物的溶解色态行为
Dilip Pandey1, Gopal Singh1, Shivendu Mishra1
1Department of Chemistry, Indian Institute of Technology, Indore, MP, India, 452020. r.abhinav@iiti.ac.in.
Dalton transactions (Cambridge, England : 2003)
|September 26, 2023
概括
基于铜的新型协调聚合物 (CPs) 具有独特的三烯胺配体,具有可调节的排放特性. 机械研磨改变了它们的发光,这表明了新型排放材料和传感器的潜力.
科学领域:
- 材料科学 材料科学 材料科学
- 无机化学 无机化学 有机化学
- 发光的光度是非常的低.
背景情况:
- 基于铜的协调聚合物 (CPs) 是有价值的排放材料.
- 有机配体显著影响CPs的发光特性.
- 三烯胺衍生物因其发射和电荷转移特性而被探索.
研究的目的:
- 合成和表征新的二甲和二甲替代的三胺联体 (L1和L2).
- 探索这些配体与Cu (I) X盐的协调化学.
- 研究由此产生的协调聚合物 (CP) 的发光特性和机械研磨的效果.
主要方法:
- 三烯胺配体L1和L2的合成.
- 与Cu (I) Br和Cu (I) Cl结合的带的协调形成1D CP.
- 合成CP的晶体学表征.
- 对发光性质的光谱分析,包括solvatochromism和对机械研磨的反应.
主要成果:
- 四种新的基于1D Cu(I) 的协调聚合物 (CP1-CP4) 已成功合成和表征.
- 带和CP表现出发光,带通过扭曲的分子内电荷转移 (TICT) 显示出溶色.
- 机械研磨引发了排放最大值的明显变化 (CP1/CP2的蓝色,CP3/CP4的红色) 和增加的排放强度,表明分子构成和聚合引起的排放现象的变化.
结论:
- 合成的基于Cu (I) 的CP表现出以体为中心的发射.
- 机械研磨可以通过改变分子排列来有效调整这些CP的发光.
- 这些发现突出了这些新型CP的潜力,作为传感应用的适应性排放材料.
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