塑造后的头发放松 - 一种动力学方法
S Breakspear1, B Noecker1, C Popescu1
1KAO Germany GmbH, Darmstadt, Germany.
International journal of cosmetic science
|September 27, 2023
概括
这项研究研究了用热和化学方法塑造头发纤维的情况. 动力分析显示,二硫化物改制是控制头发回收的关键机制,无论采用何种塑造方法.
科学领域:
- 材料科学 材料科学 材料科学
- 物理化学 物理化学
- 头发科学 头发科学
背景情况:
- 头发纤维可以使用热或化学处理来塑造.
- 了解恢复过程的动力学对于头发科学应用至关重要.
- 以前的研究还没有完全阐明塑造后头发恢复的速度控制机制.
研究的目的:
- 为了评估热和化学形状的头发纤维的时间放松过渡.
- 用动态模型来模拟恢复过程,以确定控制速度的机制.
- 为了比较不同成型方法的放松的激活能量.
主要方法:
- 头发纤维在加热板之间通过热方式塑造,并在水中通过化学方法塑造.
- 在受控的环境条件下测量了放松瞬态.
- 使用指数和对数定律的动力建模,用于模型拟合的平方余和.
主要成果:
- 塑造和恢复被建模为连续的准化学反应.
- 热形状的纤维遵循一个指数定律 (第一阶过程).
- 化学形状的纤维遵循了对数定律 (基于透理论的放松).
- 计算的激活能量对于热和化学成型方法都是相似的.
结论:
- 头发纤维回收的速率控制机制在不同的塑造方法中是一致的.
- 这种机制被认为是头发蛋白内二硫化键的重构.
- 动力分析提供了对调节头发形状恢复的分子过程的见解.
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