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Updated: Jul 15, 2025

Protocol of Electrochemical Test and Characterization of Aprotic Li-O2 Battery
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Protocol of Electrochemical Test and Characterization of Aprotic Li-O2 Battery

Published on: July 12, 2016

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溶解的LiO2还是吸附的LiO2? 在氧电池的放电过程中的活性超氧化物

Chuan Tan1, Wentao Wang1, Yuping Wu2

  • 1State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing, Jiangsu, 211816, China. cheny@njtech.edu.cn.

Faraday discussions
|September 27, 2023
PubMed
概括

氧电池的研究表明,较低的放电潜力会增加副作用和表面被动化. 在电极表面形成的中间体比溶解的更具反应性,影响电池性能.

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Electrolysis

In a galvanic cell, the electrical work is done by a redox system on its surroundings as electrons produced by the spontaneous redox reactions are transferred through an external circuit. Alternatively, an external circuit does work on a redox system by imposing a voltage sufficient to drive an otherwise nonspontaneous reaction in a process known as electrolysis. For instance, recharging a battery involves the use of an external power source to drive the spontaneous (discharge) cell reaction in...
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Ionic Bonding and Electron Transfer

Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions. 
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A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition metal cation, surrounded by ions or molecules called ligands. These ligands can be neutral molecules like H2O or NH3, or ions such as CN− or OH−. Often, the ligands act as Lewis bases, donating a pair of electrons to the central atom. These types of Lewis acid-base reactions are examples of a broad subdiscipline called coordination...
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Electrodeposition is a technique used to separate an analyte from interferents by electrochemical processes. Here, the analyte is a metal ion that can be deposited on an electrode immersed in the sample solution. The electrochemical setup consists of an anode and a cathode. When an electric current is applied to the setup, oxidation occurs at the anode. At the cathode, which consists of a large metal surface, metal ions undergo reduction and deposit onto the surface.
Electrodeposition can...
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Voltaic/Galvanic Cells

Spontaneous Chemical Reactions
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