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Electrolytes: van't Hoff Factor03:08

Electrolytes: van't Hoff Factor

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Colligative Properties of Electrolytes
The colligative properties of a solution depend only on the number, not on the identity, of solute species dissolved. The concentration terms in the equations for various colligative properties (freezing point depression, boiling point elevation, osmotic pressure) pertain to all solute species present in the solution. Nonelectrolytes dissolve physically without dissociation or any other accompanying process. Each molecule that dissolves yields one...
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Ionic Strength: Effects on Chemical Equilibria01:19

Ionic Strength: Effects on Chemical Equilibria

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The addition of an inert ionic compound increases the solubility of a sparingly soluble salt. For example, adding potassium nitrate to a saturated solution of calcium sulfate significantly enhances the solubility of calcium sulfate. Le Châtelier's principle cannot predict this shift in the equilibrium. Instead, this could be explained in terms of changes in the effective concentration of the ions in solution in the presence of added inert salt.
In this solution, the primary...
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Solubility Equilibria03:07

Solubility Equilibria

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Solubility equilibria are established when the dissolution and precipitation of a solute species occur at equal rates. These equilibria underlie many natural and technological processes, ranging from tooth decay to water purification. An understanding of the factors affecting compound solubility is, therefore, essential to the effective management of these processes. This section applies previously introduced equilibrium concepts and tools to systems involving dissolution and precipitation.
The...
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Precipitation of Ions03:11

Precipitation of Ions

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Predicting Precipitation
The equation that describes the equilibrium between solid calcium carbonate and its solvated ions is:
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Factors Affecting Solubility04:01

Factors Affecting Solubility

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Compared with pure water, the solubility of an ionic compound is less in aqueous solutions containing a common ion (one also produced by dissolution of the ionic compound). This is an example of a phenomenon known as the common ion effect, which is a consequence of the law of mass action that may be explained using Le Chȃtelier’s principle. Consider the dissolution of silver iodide:
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Solvents01:12

Solvents

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A solvent is a substance, most often a liquid, that can dissolve other substances. Here, the substance being dissolved is called a solute. When a solvent and a solute combine, they form a solution - a homogenous mixture of both the solvent and the solute. Water is a universal biological solvent. Its polar structure allows it to dissolve many other polar compounds. The ability of water to dissolve is governed by a balance between water molecules binding to each other and binding to the solute.
A...
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Preparation of Binary and Ternary Deep Eutectic Systems
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缩离子流体:基于的水溶液与深层阳性溶剂之间有什么区别?

Guillaume Zante1, Christopher E Elgar1, Katherine George1

  • 1University of Leicester, College of Science and Engineering, Leicester, LE1 7RH, UK.

Angewandte Chemie (International ed. in English)
|September 27, 2023
PubMed
概括
此摘要是机器生成的。

深度乙溶剂 (DES) 和缩盐水具有共同的特性,与流动性相关的电荷传输. 选择性金属蚀刻可以通过控制这些离子流体中的化物和水活性来实现.

关键词:
布林斯 布林斯 布林斯 布林斯深层欧性溶剂 深层欧性溶剂电化学 电化学 电化学离子液体是一种离子液体.氧化过程中的氧化.

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科学领域:

  • 材料科学 材料科学 材料科学
  • 电化学 电化学 电化学
  • 化学工程是化学工程的重要组成部分.

背景情况:

  • 深层欧特基溶剂 (DESs) 是一种具有可调节性质的新型溶剂.
  • 缩的水盐也提供可调节的水和离子活性.
  • 了解这些流体之间的特性连续性对于金属加工等应用至关重要.

研究的目的:

  • 为了研究深层阳性溶剂 (DES) 和缩盐水之间的关系.
  • 为了证明整个缩离子流体的特性连续性.
  • 探索这些流体在选择性金属蚀刻中的使用.

主要方法:

  • 研究了各种缩离子流体中的电荷传输,摩尔导电性和流动性.
  • 测量了铁 (III) 和铜 (II) 化物的扩散系数.
  • 使用这些流体对铜,银和进行了蚀刻实验.

主要成果:

  • 电荷传输是由流动性控制的,在不同的离子流体中没有不连续性.
  • 金属化物的扩散系数与流动性线性相关.
  • 金属的选择性蚀刻取决于化物和水的活动,在水活动较高时发生被动化.

结论:

  • 缩盐具有较高的化物含量和较低的粘度比DESs.
  • 由于含水量较低,DES在防止被动化方面更有效.
  • 调节化物和水活动允许选择性蚀刻混合金属废物流.