Abel de Cózar1,2, Ana Arrieta1, Iosune Arrastia1

  • 1Departamento de Química Orgánica I, Facultad de Química, Universidad del País Vasco and Donostia International Physics Center (DIPC), P. K. 1072, 20018, San Sebastián-Donostia, Spain.

ChemPlusChem
|September 27, 2023
PubMed
概括

较高阶的电循环 (1018 π电子) 可以偏离伍德沃德-霍夫曼规则. 本综述考察了这些反应,包括DFT计算,揭示了对周环拓和实验选择性的洞察.

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