通过闪电回收电池金属 热 Joule 加热
Weiyin Chen1, Jinhang Chen1, Ksenia V Bets2
1Department of Chemistry, Rice University, 6100 Main Street, Houston, TX 77005, USA.
Science advances
|September 27, 2023
概括
闪光焦耳加热快速回收离子电池 (LIB),通过稀释酸实现高金属回收. 这种环保方法减少了对环境的影响,并提高了电池回收利用的经济可行性.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 环境科学 环境科学
背景情况:
- 越来越多的退役离子电池 (LIB) 积累需要有效的回收利用.
- 关键电池金属的稀缺性要求可持续的资源管理.
- 目前的LIB回收方法在效率和环境足迹方面面临挑战.
研究的目的:
- 制定一个有效和低环境足迹的战略,从LIB中回收金属.
- 为了研究脉冲直流闪光焦耳加热 (FJH) 对于LIB回收的应用.
主要方法:
- 使用脉冲直流闪光焦耳加热 (FJH) 快速加热LIB黑质量到超过2100 K.
- 使用稀释酸 (例如0.01M HCl) 进行金属水后FJH处理.
- 进行生命周期分析,将FJH与传统回收方法进行比较.
主要成果:
- 在FJH之后,出动力学增加了1000倍.
- 在各种LIB化学品中获得了所有电池金属的高回收率.
- 证明了固体电解质间相的热分解和金属化合物的降解.
- 由于超快速加热,缓解了挥发性金属的扩散损失.
结论:
- FJH提供一种高效的LIB金属回收方法,即使使用稀释酸,也能减少二次废物.
- 与现有的回收技术相比,FJH工艺显著降低了环境足迹.
- FJH提出了一种经济上具有吸引力和可持续的方法,用于消耗的LIB处理.
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