量化活性碳部位 在气大气中的热处理过程中,在含有活性碳的氧气上化学吸收气
Atsushi Gabe1,2, Takanori Baba2, Takuma Hirahara2
1Department of Biochemistry and Applied chemistry, National Institute of Technology, Kurume College, 1-1-1, Komorino, Kurume, Fukuoka 830-8555, Japan.
Langmuir : the ACS journal of surfaces and colloids
|September 27, 2023
概括
这项研究揭示了热处理如何激活碳边缘部位用于化学吸收. 含有氧的功能组分解,产生各种化学反应至关重要的活性位点.
科学领域:
- 材料科学 材料科学 材料科学
- 表面化学 表面化学
- 催化剂是一种催化剂.
背景情况:
- 碳边缘位置对于表面反应性和电子性质至关重要.
- 了解碳的表面化学作用对于许多应用来说至关重要.
- 活性炭上含有氧的功能组会影响其反应性.
研究的目的:
- 调查在热处理过程中在活性炭上的CO产生的功能群中的氧原子的命运.
- 为了澄清化吸收活性位点的形成机制.
- 为了量化活性碳地点的含量.
主要方法:
- 采用了温度编程消化 (TPD) 和温度编程反应 (TPR) 技术.
- 热处理是在气氛中与平衡进行的.
- 用 (H2) 化学吸收来量化活性位点.
主要成果:
- 在TPR过程中观察到CO分解,通过减少释放H2O,以及二次反应产生的CO2演变.
- 对大气中的H2消耗进行了监测和表征.
- 由于CO和CO2产生的功能群的分解和自由边缘位点的激活,H2化学吸收的活性位点在大约700和1100K之间产生.
结论:
- 该研究量化地确定了化学吸收的活性点是在CO和CO2产生功能的分解后形成的.
- 醇/乙烯组被确定为这些CO产生的功能组的可能来源.
- 700K以上的热处理激活了分解的功能组和H2化学吸收的自由边缘部位.
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