不同类型的尿素溶液对废气颗粒数量排放的影响
Haohao Wang1, Tianyu Zhai2, Lijun Zhang1
1Weichai Power Co., Ltd., Weifang, 261061, People's Republic of China.
Environmental science and pollution research international
|September 27, 2023
概括
将尿素溶液添加到柴油发动机中明显增加了颗粒数排放,其影响因尿素类型而异. 尿素溶液中的金属含量显著影响颗粒数量排放因子.
科学领域:
- 汽车工程 汽车工程
- 环境科学 环境科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 柴油发动机是颗粒物 (PM) 排放的主要来源.
- 尿素在水中的溶液通常用作柴油排气液 (DEF),以减少氧化 (NOx).
- DEF对粒子数 (PN) 排放的影响需要进一步调查.
研究的目的:
- 质量评估不同水中的尿素溶液对柴油发动机颗粒数排放的影响.
- 为了确定哪些尿素类型对PN排放产生最重要的影响.
- 了解尿素溶液成分和PN排放因子之间的关系.
主要方法:
- 一个柴油发动机被 subjected to bench testing. 柴油发动机被 subjected to bench testing. 柴油发动机被 subjected to bench testing. 柴油发动机被 subjected to bench testing. 柴油发动机被 subjected to bench testing. 柴油发动机被 subjected to bench testing. 柴油发动机被 subjected to bench testing.
- 他们注射了五种不同类型的尿素在水中的溶液.
- 测量了即时颗粒度和颗粒大小分布.
- 粒子数 (PN) 排放因子为每个尿素类型计算.
主要成果:
- 与基线相比,即时颗粒度在注射尿素与水溶液时显著增加.
- 颗粒度的增加是没有溶液的0.3至1.2倍.
- 高速发动机运行显示了颗粒度的显著上升,特别是与尿素溶液C和E.
- 颗粒大小分布在尿素溶液剂量方面基本没有变化.
- PN排放因子因尿素类型而异,其序列为C > E > A > B > D.
结论:
- 在水中注射尿素溶液显然增加了柴油发动机中的颗粒数排放.
- 水中的尿素溶液中的金属元素含量是影响PN排放因子的关键因素.
- 未来的研究应该优先考虑了解与注射尿素在水溶液相关的粒子形成机制.
相关概念视频
Comparative Excretory Systems
19.4K
Animals have evolved different strategies for excretion, the removal of waste from the body. Most waste must be dissolved in water to be excreted, so an animal’s excretory strategy directly affects its water balance.
19.4K
Urea Cycle
44.8K
The urea cycle describes how liver cells convert ammonia to urea. Ammonia is a toxic waste product of protein catabolism. Land animals must convert ammonia into the less toxic urea which can be safely eliminated by the kidneys through urine. Marine animals excrete ammonia directly, and the surrounding water dilutes the ammonia to safe levels.
44.8K
The Equilibrium Constant
47.9K
Consider the oxidation of sulfur dioxide:
47.9K
2° Amines to N-Nitrosamines: Reaction with NaNO2
4.3K
Secondary amines react with nitrous acid to form N-nitrosamines, as depicted in Figure 1. Nitrous acid, a weak and unstable acid, is formed in situ from an aqueous solution of sodium nitrite and strong acids, such as hydrochloric acid or sulfuric acid, in cold conditions. In the presence of an acid, the nitrous acid gets protonated. The subsequent loss of water results in the formation of the electrophile known as nitrosonium ion.
4.3K
Urine: Physical and Chemical Properties
912
Urine comprises approximately 95% water and 5% solutes. The primary ingredient, apart from water, is urea - a byproduct of the breakdown of amino acids. Other notable components include uric acid, a residue from nucleic acid metabolism, and creatinine, a metabolite from creatine phosphate breakdown in skeletal muscle tissue.
The concentration of these solutes varies, with urea being the most abundant nitrogenous waste product. Other solutes include sodium, chloride, potassium, phosphate,...
The concentration of these solutes varies, with urea being the most abundant nitrogenous waste product. Other solutes include sodium, chloride, potassium, phosphate,...
912
1° Amines to Diazonium or Aryldiazonium Salts: Diazotization with NaNO2 Overview
3.3K
Nitrous acid and nitric acids are two types of acids containing nitrogen, among which nitrous acid is weaker than nitric acid. Nitrous acid with a pKa value of 3.37 ionizes in water to give a nitrite ion and the hydronium ion.
The nitrous acid is unstable. Hence, it is formed in situ from a solution of sodium nitrite and cold aqueous acids such as hydrochloric or sulfuric acid. In an acidic solution, the –OH group of nitrous acid undergoes protonation to give oxonium ion, followed by...
The nitrous acid is unstable. Hence, it is formed in situ from a solution of sodium nitrite and cold aqueous acids such as hydrochloric or sulfuric acid. In an acidic solution, the –OH group of nitrous acid undergoes protonation to give oxonium ion, followed by...
3.3K


