玻璃异常密度行为的起源
1Molecular Foundry of Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA.
Materials (Basel, Switzerland)
|September 28, 2023
概括
玻璃状的异常密度是由于玻璃过渡过程中形成的纳米片结构. 这些结构导致体积轻微膨胀,解释了二氧化玻璃中的密度异常.
科学领域:
- 材料科学 材料科学 材料科学
- 固态化学 固态化学
背景情况:
- 玻璃性二氧化具有异常的密度-温度关系,特别是在低氧化含量时.
- 了解这种异常对于在高温下使用玻璃的应用至关重要.
研究的目的:
- 为了解释玻璃性中的异常密度-温度关系.
- 阐明中程订单在玻璃过渡过程中的作用.
主要方法:
- 在玻璃状中分析玻璃化过渡过程.
- 结构分析侧重于中程订单及其对数量的影响.
主要成果:
- 一个中等范围的有序结构,称为"纳米片",在玻璃过渡过程中形成.
- 这些纳米片由SiO4四面体层组成,通过共价键和范德瓦尔斯键相互作用.
- 范德瓦尔斯键的形成导致体积膨胀,导致密度异常.
结论:
- 玻璃性二氧化的密度异常是从1480°C冷却到950°C冷却期间纳米片形成和生长的直接结果.
- 中等范围的订单显著影响了二氧化玻璃的热物理特性.
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