合成和评估一个添加剂的属性基于石酸盐用于水泥系统的添加剂
Svetlana V Samchenko1, Irina V Kozlova1, Andrey V Korshunov1
1Department of Building Materials, Moscow State University of Civil Engineering, 26, Yaroslavskoye Shosse, 129337 Moscow, Russia.
Materials (Basel, Switzerland)
|September 28, 2023
概括
研究人员使用二氧化-双氧化物 (TiO2-Bi2O3) 化合物开发了光催化混凝土. 使用5%重量添加剂获得最佳效果,增强强度并为可持续建筑材料提供光催化性能.
科学领域:
- 建筑材料科学 建筑材料科学
- 纳米技术 纳米技术
- 光催化作用的光催化
背景情况:
- 现代建筑材料科学专注于开发创新,可持续的材料.
- 用纳米和细分散添加剂对水泥进行修改,可以赋予独特的性能,如能效和光催化.
- 二氧化-双氧化物 (TiO2-Bi2O3) 化合物表现出光催化活性.
研究的目的:
- 通过两种不同的方法合成TiO2-Bi2O3化合物.
- 确定创建光催化混凝土的最佳方法.
- 描述由此产生的复合材料的特性.
主要方法:
- 固态合成方法用于TiO2-Bi2O3添加剂.
- 基于酸盐的合成方法用于TiO2-Bi2O3添加剂.
- 在水泥复合材料中加入合成添加剂.
主要成果:
- 复合材料含有3-10%的比斯木酸盐含量显示出光催化活性.
- 对光催化混凝土的最佳添加剂含量被确定为5重量%.
- 含有5%重量比斯木酸盐的化合物表现出强度增加 (10%固态,16%酸盐方法) 和光催化性能.
结论:
- 固态和酸盐基方法都能为混凝土生产有效的光催化剂添加剂.
- 比斯木酸盐含量为5重量%是达到增强强度和光催化活性的最佳方法.
- 开发的光催化混凝土为可持续建筑应用提供了潜力.
相关概念视频
Hydration of Cement
271
Hydration of cement is a chemical reaction between cement particles and water. This process occurs primarily through two mechanisms: through-solution and topochemical. In the through-solution process, anhydrous compounds dissolve into their constituents, hydrates form in the solution, and then precipitate from the supersaturated solution. The topochemical process involves solid-state reactions at the cement particle surface. The through-solution process dominates the topochemical process at the...
271
Types of Cement I
141
Portland cement comes in several types, each with distinct properties and applications based on their chemical composition and hydration characteristics:
Type I (Ordinary Portland Cement) is widely used for general construction where special properties are not required. It has moderate sulfate resistance and heat of hydration.
Type II (Modified Cement) offers moderate resistance to sulfate attack and a lower rate of heat development compared to Type I. It is suitable for structures in...
Type I (Ordinary Portland Cement) is widely used for general construction where special properties are not required. It has moderate sulfate resistance and heat of hydration.
Type II (Modified Cement) offers moderate resistance to sulfate attack and a lower rate of heat development compared to Type I. It is suitable for structures in...
141
Types of Cement II
124
Portland blast-furnace cement is made by blending Portland cement clinker with granulated blast-furnace slag, which accounts for 25 to 65 percent of the cement's weight. Despite its similarities to ordinary Portland (Type I) cement in terms of fineness and setting times, its early strength is lower, though it achieves comparable strength later on. It's particularly suited for mass concrete structures and marine environments due to its lower heat of hydration and superior sulfate...
124
Additives and Fillers in Concrete
110
Additives and fillers are integral to enhancing the properties of concrete. Pozzolans and blast-furnace slag are additives or admixtures due to their reactions with calcium hydroxide released during cement hydration. Fillers, which are finely ground and similar in fineness to Portland cement, improve concrete attributes such as workability density, and reduce capillary bleeding or cracking. Some fillers possess hydraulic properties or participate in benign reactions within the cement paste.
The...
The...
110
Soundness of Cement
198
The soundness of cement refers to the ability of cement paste to retain its volume after setting. Unsound cement can lead to expansion and structural damage due to the presence of free lime, magnesia, and calcium sulfate. Free lime hydrates very slowly, expanding and causing unsoundness, which is difficult to detect because it intercrystallizes with other compounds. Magnesia also reacts with water, forming crystals that can disrupt the cement's structure. Calcium sulfate can create...
198
Strength and Heat of Hydration
264
The hydration of cement is an exothermic reaction in which heat is generated as cement hydrates. This heat of hydration is critical to cement's strength development. The rate at which this heat is generated affects the temperature rise, with a majority of the heat being released early in the hydration process, half within the first three days, and about 75% within the first week.
The heat of hydration for each cement compound is significant; for instance, tricalcium aluminate (C3A) and...
The heat of hydration for each cement compound is significant; for instance, tricalcium aluminate (C3A) and...
264


