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A 'Plug and Play' Method to Create Water-dispersible Nanoassemblies Containing an Amphiphilic Polymer, Organic Dyes and Upconverting Nanoparticles
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锡南酸间接层状氧化:紫外线光敏的可切换材料

Maria A Teplonogova1, Alexey D Yapryntsev1, Alexander E Baranchikov1

  • 1Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, 119991 Moscow, Russia.

Micromachines
|September 28, 2023
PubMed
概括

研究人员使用分层的氧化和肉酸盐离子开发了对光敏感的宿主-客体材料. 紫外线改变了层间距离,显示了可切换设备的潜力.

科学领域:

  • 材料科学 材料科学 材料科学
  • 超分子化学 超分子化学
  • 纳米技术 纳米技术

背景情况:

  • 对于可切换设备来说,对刺激反应的宿主-客户材料越来越感兴趣.
  • 光是一种方便的刺激,通过客分子影响物质特性.
  • 层层的稀土氧化物与可光切换的离子相交叠是有希望的候选物.

研究的目的:

  • 为了研究分层稀土氧化物作为刺激响应材料的潜力.
  • 用肉酸来证明紫外线引起的层间距离的变化.
  • 为了探索跨和 cis-cinnamate 阳离子在层叠的氧化中的介质.

主要方法:

  • 跨-和 cis-cinnamate 离子间隔成分层的氧化.
  • 介质材料的紫外线辐射.
  • 测量层间距离的变化.

主要成果:

  • 成功地将trans和cis-cinnamate离子间隔成分层的氧化.
  • 在紫外线照射中观察到层间距离从21.9到20.6 Å的变化.
  • 证明了分层稀土氧化物对刺激的反应行为.
关键词:
切换紫外线的方法离子交换的离子交换克莱斯:克莱斯是指粘土.热水处理是一种热水处理.层层的材料 层层的材料刺激-响应的刺激.

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结论:

  • 层层的稀土氧化物可以作为刺激响应材料.
  • 像肉酸盐这样的紫外线可切换的离子可以调节层间距离.
  • 这项工作为光控制的主机-客机系统开辟了可能性.