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Updated: Jul 15, 2025

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene
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组-6组-14三键复合物与乙烯之间的 [2 + 2] 循环添加的反应性分析:理论研究的见解

Chi-Shiun Wu1, Ming-Der Su1,2

  • 1Department of Applied Chemistry, National Chiayi University, Chiayi 60004, Taiwan.

Inorganic chemistry
|September 28, 2023
PubMed
概括

理论研究表明,含有6组和14组元素的有机金属复合物与Me-CC-Ph发生 [2+2] 循环添加反应. 反应机制涉及dative键,激活障碍取决于反应物的几何结构.

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Cycloadditions are one of the most valuable and effective synthesis routes to form cyclic compounds. These are concerted pericyclic reactions between two unsaturated compounds resulting in a cyclic product with two new σ bonds formed at the expense of π bonds. The [4 + 2] cycloaddition, known as the Diels–Alder reaction, is the most common. The other example is a [2 + 2] cycloaddition.
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