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Updated: Jul 15, 2025

Preparation of Silver-Palladium Alloyed Nanoparticles for Plasmonic Catalysis under Visible-Light Illumination
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光催化解碳氧化Minisci反应由加加载化催化

Lida Tan1, Hyotaik Kang1, Mingxin Liu1,2

  • 1Department of Chemistry, and FQRNT Centre for Green Chemistry and Catalysis, McGill University, 801 Sherbrooke Street West, Montreal, QC H3A 0B8, Canada.

Precision chemistry
|September 29, 2023
PubMed
概括

这项研究引入了一种使用化光催化剂的新型光驱脱碳化Minisci反应. 这种高效的方法可以在温和的条件下直接C-H化异质.

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Alkenes via Reductive Coupling of Aldehydes or Ketones: McMurry Reaction01:22

Alkenes via Reductive Coupling of Aldehydes or Ketones: McMurry Reaction

The radical dimerization of ketones or aldehydes gives vicinal diols through a pinacol coupling reaction. However, the behavior of titanium metals used for the reaction as a source of electrons is unusual. When the reaction is carried out in the presence of titanium, diols can be isolated at low temperatures. Else titanium further reacts with diols, forming alkenes through the McMurry reaction.
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