伊塔康酸作为贝图林基热中的共体,通过序列和批量制备
Alexandra M Lehman-Chong1,2, Casey L Cox1,2, Emre Kinaci2
1Department of Chemical Engineering, Rowan University, 201 Mullica Hill Road, Glassboro, New Jersey 08028, United States.
概括
生物基单体,如伊塔康酸和贝林,被用来制造新的热聚合物. 增加伊塔康酸含量增强了这些可持续聚合物的机械和热性能.
科学领域:
- 聚合物化学 聚合物化学
- 可持续材料科学科学 可持续材料科学
- 使用可再生资源的利用.
背景情况:
- 生物基单体为聚合物生产提供了可持续的替代品.
- 伊塔康酸 (IA) 是一种多功能,商用可用的生物基单体,适合UV和热固化.
- 贝图林是树皮中的复杂二醇,由于其生物相容性,它对材料应用具有前途.
研究的目的:
- 通过使用贝林和伊塔康酸合成和表征新型热固体.
- 通过顺序和散装固化方法制备的这些热固体的结构性质关系的研究.
- 为了评估伊塔康酸含量对贝林基热的性能的影响.
主要方法:
- 使用贝林,IA和生物基二酸 (C12,C18) 合成热塑性聚前体.
- 聚甲酸盐 (PM) 树脂的配方,用于UV可固化热.
- 通过无溶剂融聚凝与糖醇交叉链接剂制备散装固化热.
- 评估机械性能 (储存模块,Tg) 和热稳定性.
主要成果:
- 顺序 UV 固化和批量固化热均成功制备.
- 增加伊塔克酸含量导致增强的储存模块,玻璃过渡温度 (Tg) 和热稳定性.
- 这项研究表明,基于IA的贝林基热具有可调节的特性.
结论:
- 伊塔科尼酸是生产可调节性特性的贝林基热的可行的共同体.
- 这些可再生热固体在聚合物材料中提供了扩展的应用.
- 这些发现支持通过生物基聚合物推进可持续制造.
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