将半古典周期轨道嵌入混乱的多体哈密尔顿主义者

Shortly after de Broglie published his ideas that the electron in a hydrogen atom could be better thought of as being a circular standing wave instead of a particle moving in quantized circular orbits, Erwin Schrödinger extended de Broglie’s work by deriving what is now known as the Schrödinger equation. When Schrödinger applied his equation to hydrogen-like atoms, he was able to reproduce Bohr’s expression for the energy and, thus, the Rydberg formula governing hydrogen spectra.

The mathematical expression known as the wave function, ψ, contains information about each orbital and the wavelike properties of electrons in an isolated atom. When atoms are bound together in a molecule, the wave functions combine to produce new mathematical descriptions that have different shapes. This process of combining the wave functions for atomic orbitals is called hybridization and is mathematically accomplished by the linear combination of atomic orbitals. The new orbitals that...

Following the work of Ernest Rutherford and his colleagues in the early twentieth century, the picture of atoms consisting of tiny dense nuclei surrounded by lighter and even tinier electrons continually moving about the nucleus was well established. This picture was called the planetary model since it pictured the atom as a miniature “solar system” with the electrons orbiting the nucleus like planets orbiting the sun. The simplest atom is hydrogen, consisting of a single proton as...

Overview of Molecular Orbital Theory

Molecular Orbital Energy Diagrams

While simple harmonic motion and uniform circular motion may be two separate concepts, they correlate and interlink with each other. Simple harmonic motion is an oscillatory motion in a system where the net force can be described by Hooke's law, while uniform circular motion is the motion of an object in a circular path at constant speed.
There is an easy way to produce simple harmonic motion by using uniform circular motion. For instance, consider a ball attached to a uniformly rotating...