揭开深度化碳的持久性:从有机物质表征的洞察力
Ryan E Champiny1, Allan R Bacon1, Isabella D Brush1
1Department of Soil, Water, and Ecosystem Science, University of Florida, Gainesville, FL 32611, USA.
The Science of the total environment
|September 29, 2023
概括
美国土壤中的深度波兹罗化碳 (DPC) 储存是巨大的. 深层土壤中的表水位波动减缓了微生物降解,促进了碳的积累和持久性.
科学领域:
- 土壤科学 土壤科学
- 生物地质化学生物地质化学
- 环境科学 环境科学
背景情况:
- 超过10亿的陆地碳 (C) 储存在美国东南部沿海平原的深层土壤中,形成了深度化碳 (DPC) 池.
- 稳定这一重要的碳池的机制仍然不清楚,这阻碍了我们了解其持久性的理解.
研究的目的:
- 为了研究深化碳 (DPC) 的稳定机制.
- 为了测试水文学的假设,特别是水表波动,驱动DPC积累和持久性.
主要方法:
- 使用元素分析,溶剂提取,红外光谱学和高分辨率质谱学对DPC有机物质进行表征.
- 批量和溶解有机物分量的分析,以评估组成和可变性.
主要成果:
- DPC有机物在很大程度上可以通过酸盐提取,金属的结合会影响水可提取的分数.
- 低分子量水中可提取物种显示氧化状态的变化,表明氧气限制.
- 红外光谱检测显示,随着DPC的深度,亚利法键的增加和芳香键的减少.
- 发现DPC比表面土壤碳更耐火,但比表面的地下土壤更不稳定.
结论:
- 水文控制,特别是持续的水和和低氧化还原条件,对DPC的稳定和持久性做出了重大贡献.
- 这些发现为该地区的深层和浅层化碳提供了机制的区别.
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