基于非向分析,对有机化合物在全面填埋场污水处理过程中的分子特性进行研究
Ninghui Song1, Qian Zhang2, Yixuan Wang1
1Nanjing Institute of Environmental Sciences, Ministry of Ecology and Environment, Nanjing, 210042, PR China.
Environmental research
|September 29, 2023
概括
一种使用GC×GC-QTOF-MS进行垃圾填埋污水分析的新方法揭示了2508种有机化合物,其中包括17种新出现的污染物. 在A2O-MBR-NF过程中,去除了79%的化合物,无氧处理是关键.
科学领域:
- 环境化学环境化学
- 分析化学 分析化学
- 环境工程 环境工程
背景情况:
- 垃圾填埋场的液由于复杂的有机化合物而造成环境风险.
- 在分子层面评估治疗过程对于优化至关重要.
- 液中新出现的污染物需要准确的检测和清除评估.
研究的目的:
- 提出一种新的方法来评估垃圾填埋场水处理,使用非向分析.
- 在分子水平上评估A2O-MBR-NF过程的去除效率.
- 识别和量化垃圾填埋场中的新出现的污染物.
主要方法:
- 使用全面的二维气体染色学四极飞行时间质谱法 (GC×GC-QTOF-MS) 的非目标分析.
- 检测到的有机化合物的多级分类.
- 在A2O-MBR-NF处理过程中的不同化合物类的去除速率的评估.
主要成果:
- 总共有2508种有机化合物被确定,包括17种新兴污染物,如DIBP和4-Tert-Butylphenol.
- 在A2O-MBR-NF过程中,有机化合物的整体去除率达到79.14%.
- 无氧治疗对去除有显著的贡献 (64.98%),对异环化合物的效率高 (94.67%),但对异环化合物的效率较低 (63.49%).
结论:
- 拟议的非向分析方法准确地评估了分子层面的处理过程.
- A2O-MBR-NF过程证明了有效地去除许多有机化合物,但需要优化阿里法特.
- 这种方法为废物处理厂的优化和新出现的污染物监测提供了宝贵的见解.
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