关于中国三种不同煤炭样本的燃烧,热解特征和动力学的实验研究
Chang Li1, Zhengdong Liu2, Chunmiao Yuan2
1Department of Civil Engineering, Shenyang Jianzhu University, Shenyang 110168, China.
ACS omega
|October 2, 2023
概括
炭石煤很难点燃,但由于活性能量更高,其热失控风险较低. 矿和煤在工业应用中需要采取更大的安全预防措施.
科学领域:
- * 燃烧科学与工程.
- * 化学动力学和热力学.
背景情况:
- *煤炭的热和运动参数对于设计燃烧反应堆和评估风险至关重要.
- *了解这些参数对于安全有效地利用各种煤炭类型至关重要.
研究的目的:
- * 为了研究煤,煤和炭化煤样品的热和运动参数.
- * 为了比较与不同类型的煤相关的燃烧行为和点火风险.
主要方法:
- *热重力测量 (TG) 和差分扫描热量测量 (DSC) 用于分析燃烧阶段和温度间隔.
- *篮子加热方法来确定动力数据,包括激活能量.
- * 粉尘层的最小点火温度 (MITL) 测试,以验证热失控风险.
主要成果:
- *所有煤炭类型都表现出两种不同的燃烧阶段,反应间隔转移到较高的温度,从煤到炭 (317665 °C).
- * 炭石表现出更高的激活能 (4967 kJ/mol) 和反应热 (22.6 kJ/kg),表明点火难,但热失控风险较低.
- *石灰岩和煤的激活能量较低,这表明热失控的风险更高.
结论:
- *与煤和煤相比,炭酸煤具有较低的热逃跑风险.
- * 石灰和煤需要在工业环境中加强安全措施.
- * 该研究为危险分析和高效燃煤反应堆的设计提供了有价值的数据.
更多相关视频
相关概念视频
Combustion Energy: A Measure of Stability in Alkanes and Cycloalkanes
6.4K
The low reactivity in alkanes can be attributed to the non-polar nature of C–C and C–H σ bonds. Alkanes, therefore, were initially termed as “paraffins,” derived from the Latin words: parum, meaning “too little,” and affinis, meaning “affinity.”
Alkanes undergo combustion in the presence of excess oxygen and high-temperature conditions to give carbon dioxide and water. A combustion reaction is the energy source in natural gas, liquified...
Alkanes undergo combustion in the presence of excess oxygen and high-temperature conditions to give carbon dioxide and water. A combustion reaction is the energy source in natural gas, liquified...
6.4K
Enthalpy and Heat of Reaction
8.5K
Combustion, commonly known as burning, is a reaction in which a substance reacts with an oxidizing agent, which in most cases is molecular oxygen, to liberate energy in the form of heat, light, or sound. The heat of combustion is also known as the enthalpy of combustion. The energy released when one mole of a substance undergoes complete combustion at constant pressure is called molar heat of combustion. Combustion reactions are exothermic; that is, they release energy, and their ΔH sign...
8.5K
Constant Volume Calorimetry
27.2K
Calorimeters are useful to determine the heat released or absorbed by a chemical reaction. Coffee cup calorimeters are designed to operate at constant (atmospheric) pressure and are convenient to measure heat flow (or enthalpy change) accompanying processes that occur in solution at constant pressure. A different type of calorimeter that operates at constant volume, colloquially known as a bomb calorimeter, is used to measure the energy produced by reactions that yield large amounts of heat and...
27.2K
Flame Photometry: Overview
649
Flame photometry, also known as flame emission spectrometry, is a technique used for the qualitative and quantitative analysis of elements present in a sample using a flame as the source of excitation energy. The concept of flame photometry was realized in the early 1860s by Kirchhoff and Bunsen, who discovered that specific elements emit characteristic radiation when excited in flames. The first instrument developed for this purpose was used to measure sodium (Na) in plant ash using a Bunsen...
649


