Al@SiO2核心外填充剂提高了复合材料的介电性能
Bin Huang1, Yan Yu1,2, Yan Zhao1,2
1Key Laboratory of Science and Technology on High-Tech Polymer Materials, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China.
ACS omega
|October 2, 2023
概括
研究人员开发了带有Al@SiO2核心外填充剂的复合材料,显著提高软电活性材料的介电常数和电分解强度.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物科学 聚合物科学
- 电气工程 电气工程
背景情况:
- 基于聚氧的介电弹性体是有前途的软电活性材料.
- 聚二甲基素的低导电性限制了实际应用.
- 需要在软电活性材料中增强介电性质.
研究的目的:
- 开发具有增强介电性能的高性能复合材料.
- 为了研究核心外填充结构对介电行为的影响.
- 为了提高电常数和的分解强度.
主要方法:
- 制造具有控制核心外填充特性的/Al@SiO2复合材料.
- 对介电性能的研究,包括介电常数和损耗.
- 介电松过程的分析,特别是麦克斯韦-瓦格纳-西拉斯 (MWS) 松.
- 对MWS放松时间的温度依赖性的研究.
主要成果:
- 实现了高介电常数,低介电损耗和高电断裂强度.
- 核心外填充剂增强了MWS放松过程.
- 在复合材料中减少了直流电导损失.
- 随着温度变化,MWS放松时间遵循阿雷尼乌斯方程.
结论:
- 控制外层厚度和核心外填充剂含量是优化复合材料性能的关键.
- 核心外结构填充剂有效地提高了复合材料的导电性.
- 这一战略为开发其他高介电常数材料提供了途径.
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