制备,热储性能和酸三水合物/扩张石墨复合物相变材料的应用
K W Wang1,2, Ting Yan1,2, L C Meng1,2
1College of Energy and Mechanical Engineering, Shanghai University of Electric Power, Shanghai 201306, China. yanting@shiep.edu.cn.
Dalton transactions (Cambridge, England : 2003)
|October 2, 2023
概括
这项研究开发了使用扩展石墨 (EG) 和酸盐三水合物 (SAT) 的复合相变材料 (CPCM),以提高导热率并防止泄漏,以有效储存热能.
科学领域:
- 材料科学 材料科学 材料科学
- 储能 储能 储能 储能 储能 储能
- 化学工程是化学工程的重要组成部分.
背景情况:
- 使用相变材料 (PCM) 的潜热储存对于高效的能源使用和可持续发展至关重要.
- 固体-液体PCM面临着诸如低导热率,稳定性差,泄漏等挑战,阻碍了广泛应用.
- 复合相变材料 (CPCM) 通过将支材料与PCM集成来提供解决方案.
研究的目的:
- 开发和描述基于三水酸 (SAT) 和扩展石墨 (EG) 的新型复合相变材料 (CPCM).
- 为了提高SAT的导热性和稳定性,同时减轻泄漏问题.
- 研究CPCM在热能存储应用中的潜力,包括一个原型烤箱.
主要方法:
- 复合相变材料 (CPCM) 是通过将扩展石墨 (EG) 与酸三水合物 (SAT) 结合而合成的.
- 描述涉及扫描电子显微镜 (SEM),富里埃变换红外光谱学 (FTIR),X射线衍射 (XRD),导热分析和微分扫描热量计 (DSC).
- 为了评估性能,进行了循环稳定性测量和原型烤箱测试.
主要成果:
- SEM证实EG的多孔结构有效吸附SAT,XRD和FTIR表明物理组合.
- 与纯SAT相比,SAT/EG CPCM的导热率增加了205.1%,超冷却减少了.
- 添加剂如二二二甲 (DHPD) 和凝进一步改善了超冷却和分相抑制.
- 一个原型烤箱使用开发的CPCM证明了有效的热储和释放.
结论:
- 开发的SAT/EG CPCM显示了潜在热储存的显著增强的导热性和稳定性.
- 结合EG有效地解决了固体液体PCM中的泄漏问题.
- 添加核和加厚剂进一步优化了PCM性能.
- 这些发现支持这些CPCM在热能存储系统 (如烤箱) 中的实际应用.
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