Ba4Si6O16:Eu2+,RE光体的发光和机械发光
Alexis Duval1, Yan Suffren2, Mourad Benabdesselam3
1Glass Mechanics Lab., IPR (Institut de Physique de Rennes), UMR 6251, University of Rennes, Campus de Beaulieu, Rennes, France.
The Journal of chemical physics
|October 2, 2023
概括
这项研究研究了绿色 (Ba4Si6O16:Eu2+,稀土) 的发光. 对它们的长时间和机械发光性质的新见解被揭示出来,提出了一个新的机制.
科学领域:
- 材料科学 材料科学 材料科学
- 固态化学 固态化学
- 发光的光度是非常的低.
背景情况:
- 与欧 (Eu2+) 和稀土 (RE) 合的酸盐具有独特的光学特性.
- 了解发光机制对于开发先进的照明和传感材料至关重要.
研究的目的:
- 报告绿色Ba4Si6O16:Eu2+,RE光体的发光特性.
- 为了研究它们的长期光和机械发光.
- 为 RE = Ho3+ 化光剂提出一种新的发光机制.
主要方法:
- 合成和描述Ba4Si6O16:Eu2+,RE的.
- 热刺激发光 (TSL) 实验,以确定陷深度和度.
- 低温光谱学用于分析排放频段.
- 机械装载和卸载实验,以研究机械发光.
主要成果:
- 详细介绍了Ba4Si6O16:Eu2+,RE光体的发光性能.
- 长时间的光与陷特征相关.
- 由于Eu2+在不同的Ba2+地点,在低温下观察到一个新的439nm发射波段.
- 针对RE=Ho3+提出了一种涉及陷分布 (0.6940.924 eV) 的新型发光机制.
结论:
- 这项研究阐明了Ba4Si6O16:Eu2+,RE光体的发光行为.
- 拟议的机械发光机制为材料对机械应力反应提供了新的理解.
- 这些体显示出需要在机械刺激下发射光的应用的潜力.
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