全球有机和无机气溶的高度性及其对辐射强迫的影响
Mira L Pöhlker1,2,3, Christopher Pöhlker4, Johannes Quaas5
1Multiphase Chemistry Department, Max Planck Institute for Chemistry, 55128, Mainz, Germany. poehlker@tropos.de.
Nature communications
|October 2, 2023
概括
全球测量显示,可以使用有机和无机质量分数来预测气溶的高度 (κ). 这一发现通过提供有机 (κorg) 和无机 (κinorg) 成分的平均湿度值来完善气候模型.
科学领域:
- 大气化学和物理大气化学和物理
- 气候科学 气候科学
- 气溶科学 气溶科学
背景情况:
- 大气中的气溶颗粒充当云凝结核 (CCN),影响气候.
- CCN的气候影响取决于化学成分和湿度,这两者各不相同.
- 对CCN属性的准确表示对于气候建模至关重要.
研究的目的:
- 呈现全球测量CCN属性在不同的环境.
- 建立一种方法,从化学成分中推导出有效的气溶高度 (κ).
- 限制全球气候建模的关键参数.
主要方法:
- 在各种环境条件下进行全球CCN测量.
- 使用有机物质 (εorg) 和无机离子 (εinorg) 的质量分数,推导出有效的气溶高度 (κ).
- 有机 (κorg) 和无机 (κinorg) 成分的量化平均湿度度值.
主要成果:
- 开发了一个线性模型: κ = εorg⋅κorg + εinorg⋅κinorg.
- 确定了全球平均值: κorg = 0.12 ± 0.02 和 κinorg = 0.63 ± 0.01.
- 表明全球气候强迫对 κorg 和 κinorg.org 的变化极少敏感.
结论:
- 从气溶的化学成分可以准确地预测气溶的高度.
- 已确定有机和无机成分的全球平均高度值.
- 这项研究为改善全球气候模型提供了关键的限制.
相关概念视频
Gravimetry: Inorganic And Organic Precipitating Agents
1.3K
In gravimetry, the precipitant is chosen carefully to obtain a pure solid that can be easily filtered. Common inorganic precipitants can be used to determine several cations and anions. In some cases, the formation of the same precipitate can be used to determine the cation and the anion. For example, the reaction of barium and chromate ions to give barium chromate is used to determine both barium and chromate. However, precipitates such as hydroxides, oxalates, and metal ammonium phosphates...
1.3K
Precipitation Processes
483
The experimental conditions in a gravimetric analysis should be optimized to maximize the particle size and purity of the obtained precipitate. Ideally, the concentration of the precipitating reagent should be low with effective stirring to maintain low relative supersaturation for the growth of large crystals. In homogeneous precipitation, the precipitant is slowly generated by a chemical reaction in the solution to avoid local reagent excesses. For example, urea decomposes gradually to...
483
Global Climate Change
24.4K
Throughout its ~4.5 billion year history, the Earth has experienced periods of warming and cooling. However, the current drastic increase in global temperatures is well outside of the Earth’s cyclic norms, and evidence for human-caused global climate change is compelling. Paleoclimatology, the study of ancient climate conditions, provides ample evidence for human-caused global climate change by comparing recent conditions with those in the past.
24.4K
Real Gases: Effects of Intermolecular Forces and Molecular Volume Deriving Van der Waals Equation
34.7K
Thus far, the ideal gas law, PV = nRT, has been applied to a variety of different types of problems, ranging from reaction stoichiometry and empirical and molecular formula problems to determining the density and molar mass of a gas. However, the behavior of a gas is often non-ideal, meaning that the observed relationships between its pressure, volume, and temperature are not accurately described by the gas laws.
34.7K
Precipitation and Co-precipitation
1.8K
Precipitation and coprecipitation methods can be used to separate a mixture of ions in a solution. In qualitative inorganic analysis, ions that form sparingly soluble precipitates with the same reagent are separated based on the differences in solubility products. For example, consider the separation of Cu(II) and Fe(II) ions by precipitation as insoluble sulfides. First, copper(II) sulfide is precipitated by the addition of acidic H2S, where the dissociation of H2S is suppressed. Adding H2S...
1.8K
Precipitation of Ions
28.0K
Predicting Precipitation
The equation that describes the equilibrium between solid calcium carbonate and its solvated ions is:
The equation that describes the equilibrium between solid calcium carbonate and its solvated ions is:
28.0K


