证据表明,在Mg-struvite形成的早期阶段,液体与液体相分离
Stephanos Karafiludis1,2, Ernesto Scoppola3, Stephan E Wolf4
1Federal Institute for Materials Research and Testing (BAM), Richard-Willstatter-Straße 11, 12489 Berlin, Germany.
The Journal of chemical physics
|October 3, 2023
概括
斯特鲁维特的降水从废水中回收. 这项研究揭示了一个非经典的结晶路径,涉及液体-液体相分离和 struvite 形成之前的无形前体.
科学领域:
- 材料科学 材料科学 材料科学
- 环境科学 环境科学
- 晶体学 晶体学是指结晶学.
背景情况:
- 斯特鲁维特 (氨酸六水合物) 沉是废水中回收的关键.
- 目前对 struvite 形成机制,特别是核和结晶的理解是有限的.
- 有证据表明,非经典的结晶路径涉及无形前体.
研究的目的:
- 阐明 struvite 形成的早期阶段机制.
- 研究无形前体在Mg-struvite结晶中的作用.
- 了解岩沉中的核化和生长过程.
主要方法:
- 基于同步射线的现场X射线散射用于时间解析的结构分析.
- 低温传输电子显微镜 (cryo-TEM) 用于高分辨率成像.
- 对散射数据的分析,以探测水性介质的结构和波动.
主要成果:
- 观察到的奥恩斯坦-泽尼克波动 (大约. 在结晶开始时,在水性介质中的1nm) 的度.
- 将这些波动解释为液态-液态相隔离的迹象.
- 通过冷-TEM证实了短暂的无形前体阶段 (>10秒) 的存在,先于Mg-struvite晶体的生长.
结论:
- 斯特鲁维特的形成遵循非经典的结晶路径.
- 液-液相分离驱动无形前体的形成.
- 这种无形相是废水中Mg-struvite沉的关键中间体.
更多相关视频
11:50Metal-silicate Partitioning at High Pressure and Temperature: Experimental Methods and a Protocol to Suppress Highly Siderophile Element Inclusions
Published on: June 13, 2015
12.6K
11:14Two-way Valorization of Blast Furnace Slag: Synthesis of Precipitated Calcium Carbonate and Zeolitic Heavy Metal Adsorbent
Published on: February 21, 2017
12.4K
相关概念视频
Qualitative Analysis
22.4K
For solutions containing mixtures of different cations, the identity of each cation can be determined by qualitative analysis. This technique involves a series of selective precipitations with different chemical reagents, each reaction producing a characteristic precipitate for a specific group of cations. Metal ions within a group are further separated by varying the pH, heating the mixture to redissolve a precipitate, or adding other reagents to form complex ions.
For instance, group IV...
For instance, group IV...
22.4K
Recrystallization: Solid–Solution Equilibria
1.1K
Recrystallization is a purification technique used to separate impurities from solid compounds. In this technique, no chemical reactions occur. Instead, it exploits physical properties only, specifically, the solubility differences between the desired compound and impurities, either at a single temperature or at different temperatures, and under other selected conditions. The solid-solution equilibrium (solubility equilibrium) of each component in the solution represents a binary phase...
1.1K
Washing, Drying, and Ignition of Precipitates
946
After filtration, the precipitate is washed to remove coprecipitated impurities and any remaining mother liquor. Colloidal precipitates, such as silver chloride, are washed with an electrolyte (such as dilute nitric acid) to prevent the peptization of the precipitate. In the case of slightly soluble precipitates, the wash solution contains a common ion to reduce solubility. Lead sulfate, which is slightly soluble in water, is washed with dilute sulfuric acid. Similarly, wash solutions may be...
946
Extraction: Advanced Methods
481
Metal ions can be separated from one another by complexation with organic ligands–the chelating agent– to form uncharged chelates. Here, the chelating agent must contain hydrophobic groups and behave as a weak acid, losing a proton to bind with the metal. Since most organic ligands used in this process are insoluble or undergo oxidation in the aqueous phase, the chelating agent is initially added to the organic phase and extracted into the aqueous phase. The metal-ligand complex is...
481
