两个结构不同的聚合物从单个单体
Javed R Pathan1, Subhrajyoti Bhandary1, Kana M Sureshan1
1School of Chemistry, Indian Institute of Science Education and Research Thiruvananthapuram, Vithura, Thiruvananthapuram 695551, India.
Journal of the American Chemical Society
|October 3, 2023
概括
研究人员合成了一种新型的malonamide单体,用于拓化学聚合,通过亚-循环添加产生了两种不同的尼龙类聚合物,具有不同的结构和拓. 这项突破性工作使得聚合物结构能够精确控制.
科学领域:
- 聚合物化学
- 材料科学
- 晶体学
背景情况:
- 拓化学聚合提供了具有受控结构的晶体聚合物的途径.
- 酸循环添加是一种用于聚合物合成的多功能点击化学反应.
研究的目的:
- 设计和合成用于高化学聚合的马洛纳胺衍生单体.
- 从单个单体中研究两种不同的聚合物结构的形成.
- 阐明聚合过程的原子级细节和由此产生的聚合物拓.
主要方法:
- 一种具有亚酸和酸功能的马洛纳胺单体的合成.
- 结晶以获得两个多态 (M1和M2).
- 单晶X射线衍射分析晶体结构和聚合途径.
- 用热分析来诱导高化学聚合.
主要成果:
- 获得了两个单体的同时多态 (M1和M2).
- 这两种聚合物都经历了高化学酸循环添加聚合.
- 聚合物M1产生了一个1,4-非替代的三结合聚合物,聚合物垂直于键.
- 聚合物M2产生了一种1,5异位的三结合聚合物,并沿着键聚合.
- 通过单晶到单晶转换合成了具有不同拓的两个结构异构聚合物.
结论:
- 这项研究报告了从单个单体中构成两种结构异构聚合物的首次拓化学合成.
- 晶体包装决定了产生的聚合物的区域化学和拓学.
- 单晶对单晶聚合提供了对聚合物形成的原子分辨率见解.
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