凝液滴的表面应力和形状松
J Godefroid1,2, D Bouttes2, A Marcellan1
1Soft Matter Science and Engineering, ESPCI Paris, PSL Research, CNRS, Sorbonne Université, 75005 Paris, France. cecile.monteux@espci.fr.
Soft matter
|October 4, 2023
概括
固化的滴滴因表面凝结和体积收缩而放松成球体. 这个过程由不断变化的应力和曲刚性来控制,为材料形状演变提供了规则.
科学领域:
- 材料科学 材料科学 材料科学
- 软物质物理学 软物质物理学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 固化涉及复杂的运输,相位过渡和机械应变.
- 软固体中的异质变形诱导弹性应力,导致表面不稳定性和形状变化.
研究的目的:
- 在表面诱导固化过程中研究聚合物和颗粒悬浮液滴的形状演变.
- 了解拉伸应力,液体核心流量和膜度在决定最终形状的相互作用.
主要方法:
- 对滴水形状变化的实验观测.
- 数字模拟以建模凝固过程和应力演变.
- 凝层形成及其对滴滴形态的影响的分析.
主要成果:
- 由于凝剂向内扩散,在滴水表面形成一个凝层.
- 凝层内的体积收缩会引发拉伸应力,推动液体核心流动和放松到球形.
- 增长的凝膜的曲刚度最终平衡了表面应力,阻止了形状放松.
结论:
- 该研究提供了可概括的规则,用于预测固化材料的形状.
- 结合了张力和曲驱动的变形,以解释凝系统中的形状演变.
- 提供了适用于生物形态发生和工业材料加工的见解.
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