聚类触发的排放 含胆固醇的液晶聚合物:可调节的圆形极化发光和室温光
Mengdie Zhou1, Jiafan Zhang1, Yueyue Chen1
1Key Laboratory of Polymeric Materials and Application Technology of Hunan Province, Key Laboratory of Advanced Organic Functional Materials of Colleges and Universities of Hunan Province, College of Chemistry, Xiangtan University, Xiangtan, Hunan Province, 411105, China.
Macromolecular rapid communications
|October 4, 2023
概括
开发了具有集群触发发射 (CTE) 的状液晶. 性聚合物薄膜由于其螺旋结构而显示出高效的圆极化发光 (CPL),而性聚合物薄膜则表现出光.
科学领域:
- 材料科学 材料科学 材料科学
- 光物理学的光学物理学
- 聚合物化学 聚合物化学
背景情况:
- 聚合触发发射 (CTE) 材料因其独特的光物理性质而受到关注.
- 现有的CTE材料往往缺乏奇拉性,阻碍了高不对称性因子 (glum) 的高效循环极化发光 (CPL) 的发展.
研究的目的:
- 设计和合成表现出CTE的性液晶,以获得高效的CPL.
- 为了研究液晶相结构,性和CPL特性之间的关系.
主要方法:
- 一种侧链液晶聚合物 (PM6Chol) 的合成,其中包含胆固醇集群oluminogens.
- 使用不同的方法制备PM6Chol涂层和热处理薄膜.
- 液晶相的表征,发光和CPL特性.
主要成果:
- 这两种聚合物薄膜都表现出CTE和激发波长依赖的发光.
- 覆盖PM6Chol的薄膜形成了一种性双层的性C相,发射高效的CPL (高达1.0×10-1).
- 经PM6Chol热处理的薄膜形成了一种双层甲基质的smectic A阶段,不显示CPL,但呈现室温光 (2.0秒后照).
结论:
- 状液晶结构对于在CTE材料中实现高效的CPL至关重要.
- 在C阶段的螺旋式排列使得高glum值.
- 螺旋结构的缺失在状状A阶段阻止了CPL,但允许光.
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