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Updated: Jul 15, 2025

Synthesis of a Borylated Ibuprofen Derivative Through Suzuki Cross-Coupling and Alkene Boracarboxylation Reactions
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Published on: November 30, 2022

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通过轻微而高效的Pd催化形成与酸的B-C键,使多德卡酸的功能化

Mahmoud K Al-Joumhawy1, Jui-Chi Chang1, Khaleel I Assaf2

  • 1School of Science, Constructor University, Campus Ring 1, 28759, Bremen, Germany.

Chemistry (Weinheim an der Bergstrasse, Germany)
|October 4, 2023
PubMed
概括

研究人员开发了一种新的方法,通过B-C键将无机二二甲酸盐与有机分子联系起来. 这种木-米亚乌拉合方法可以创建用于各种应用的新型混合有机-无机材料.

关键词:
鈴木-宮村交叉合器的使用十二甲酸盐是什么意思 十二甲酸盐电子捐赠的电子捐赠电子提取 - 提取电子溶剂溶剂的使用方法

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In addition to the oxymercuration–demercuration method, which converts the alkenes to alcohols with Markovnikov orientation, a complementary hydroboration-oxidation method yields the anti-Markovnikov product. The hydroboration reaction, discovered in 1959 by H.C. Brown, involves the addition of a B–H bond of borane to an alkene giving an organoborane intermediate. The oxidation of this intermediate with basic hydrogen peroxide forms an alcohol.
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A significant aspect of hydroboration–oxidation is the regio- and stereochemical outcome of the reaction.
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The Diels–Alder reaction is an example of a thermal pericyclic reaction between a conjugated diene and an alkene or alkyne, commonly referred to as a dienophile. The reaction involves a concerted movement of six π electrons, four from the diene and two from the dienophile, forming an unsaturated six-membered ring. As a result, these reactions are classified as [4+2] cycloadditions.
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