解脱和在丰富的NMC阴极的阳离子氧化还原活性中的作用
Biao Li1,2,3, Zengqing Zhuo4, Leiting Zhang5
1Chimie du Solide-Energie, UMR 8260, Collège de France, Paris, France.
Nature materials
|October 5, 2023
概括
在富含的分层氧化物阴极中优于,增强了阳离子氧化还原和提高性能. 这项研究指导着用于高容量电池的先进阴极材料的开发.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 富含的多层过渡金属氧化物 (富含的NMC) 由于阳离子氧化还原化学表现出高容量.
- 丰富的NMC中氧还氧化过程的精确作用仍然未得到充分探索,限制了性能优化.
- 了解电离子贡献对于释放这些先进的阴极材料的全部潜力至关重要.
研究的目的:
- 解和阐明和在丰富的NMC中对氧化还原机制的独特影响.
- 研究阴极性能中的阴离子和阴离子氧化还原过程之间的相互作用.
- 确定最佳的组成策略,以提高丰富的NMC阴极性能.
主要方法:
- 对两个富含的NMC化合物的比较研究:Li1.2Ni0.2Mn0.6O2和Li1.2Co0.4Mn0.4O2.
- 通过电化学表征来分析阴离子和阳离子氧化还原贡献.
- 研究电荷转移机制及其对材料稳定性的影响.
主要成果:
- Ni3+/4+和Co4+都作为中间物种,通过连接物到金属的电荷转移促进氧氧还氧化.
- 增强了联体到金属的电荷转移动力学,但导致过渡金属迁移,氧气释放和电压衰减的增加.
- 与相比,表现出更有利的平衡,促进氧氧氧化还原,改善了循环稳定性.
结论:
- 是优于的首选元素,用于优化丰富的NMC中的阳离子氧化还原.
- 向富含的配方进行组合调整为高容量阴极开发提供了一个有前途的途径.
- 这项研究为设计具有优越电化学性能的下一代正极材料提供了关键的见解.
更多相关视频
07:55Elemental-sensitive Detection of the Chemistry in Batteries through Soft X-ray Absorption Spectroscopy and Resonant Inelastic X-ray Scattering
Published on: April 17, 2018
12.8K
10:57Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction
Published on: April 10, 2018
18.3K
相关概念视频
Ladder Diagrams: Redox Equilibria
467
Ladder diagrams are useful tools for understanding redox equilibrium reactions, especially the effects of concentration changes on the electrochemical potential of the reaction. The vertical axis in the redox ladder diagrams represents the electrochemical potential, E. The area of predominance is demarcated using the Nernst equation.
Consider the Fe3+/Fe2+ half-reaction, which has a standard-state potential of +0.771 V. At potentials more positive than +0.771 V, Fe3+ predominates, whereas Fe2+...
Consider the Fe3+/Fe2+ half-reaction, which has a standard-state potential of +0.771 V. At potentials more positive than +0.771 V, Fe3+ predominates, whereas Fe2+...
467
Electrodeposition
652
Electrodeposition is a technique used to separate an analyte from interferents by electrochemical processes. Here, the analyte is a metal ion that can be deposited on an electrode immersed in the sample solution. The electrochemical setup consists of an anode and a cathode. When an electric current is applied to the setup, oxidation occurs at the anode. At the cathode, which consists of a large metal surface, metal ions undergo reduction and deposit onto the surface.
Electrodeposition can...
Electrodeposition can...
652
Formation of Complex Ions
23.7K
A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition metal cation, surrounded by ions or molecules called ligands. These ligands can be neutral molecules like H2O or NH3, or ions such as CN− or OH−. Often, the ligands act as Lewis bases, donating a pair of electrons to the central atom. These types of Lewis acid-base reactions are examples of a broad subdiscipline called coordination...
23.7K
Redox Equilibria: Overview
575
A reduction-oxidation reaction is commonly called a redox reaction. In a redox reaction, electrons are transferred from one species to another rather than being shared between or among atoms. The reducing agent or reductant is the species that loses electrons and gets oxidized in the process. The species that gains electrons and gets reduced in the process is the oxidizing agent or oxidant. Redox reactions are represented as two separate equations called half-reactions, where one equation...
575
Voltaic/Galvanic Cells
57.5K
Spontaneous Chemical Reactions
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
57.5K
Balancing Redox Equations
52.5K
Electrochemistry is the science involved in the interconversion of electrical and chemical reactions. Such reactions are called reduction-oxidation, or redox reactions. These important reactions are defined by changes in oxidation states for one or more reactant elements and include a subset of reactions involving the transfer of electrons between reactant species. Electrochemistry as a field has evolved to yield sufficient insights on the fundamental principles of redox chemistry and multiple...
52.5K
