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相关概念视频

Electrolyte and Nonelectrolyte Solutions02:21

Electrolyte and Nonelectrolyte Solutions

63.2K
Substances that undergo either a physical or a chemical change in solution to yield ions that can conduct electricity are called electrolytes. If a substance yields ions in solution, that is, if the compound undergoes 100% dissociation, then the substance is a strong electrolyte. Complete dissociation is indicated by a single forward arrow. For example, water-soluble ionic compounds like sodium chloride dissociate into sodium cations and chloride anions in aqueous solution.
63.2K
Ionic Bonding and Electron Transfer02:48

Ionic Bonding and Electron Transfer

41.7K
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions. 
41.7K
Ionic Crystal Structures02:42

Ionic Crystal Structures

14.4K
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
14.4K
Solubility of Ionic Compounds02:55

Solubility of Ionic Compounds

63.3K
Solubility is the measure of the maximum amount of solute that can be dissolved in a given quantity of solvent at a given temperature and pressure. Solubility is usually measured in molarity (M) or moles per liter (mol/L). A compound is termed soluble if it dissolves in water.
63.3K
Electrolytes: van't Hoff Factor03:08

Electrolytes: van't Hoff Factor

33.2K
Colligative Properties of Electrolytes
The colligative properties of a solution depend only on the number, not on the identity, of solute species dissolved. The concentration terms in the equations for various colligative properties (freezing point depression, boiling point elevation, osmotic pressure) pertain to all solute species present in the solution. Nonelectrolytes dissolve physically without dissociation or any other accompanying process. Each molecule that dissolves yields one...
33.2K
Ionic Strength: Overview01:12

Ionic Strength: Overview

1.5K
The ionic strength of a solution is a quantitative way of expressing the total electrolyte concentration of a solution. This concept was first introduced in 1921 by two American physical chemists, Gilbert N. Lewis and Merle Randall, while describing the activity coefficient of strong electrolytes. During the calculation of ionic strength (I or μ), all the cations and anions are considered. However, the concentration (c) of an ion with a greater charge number (z) has a greater contribution...
1.5K

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相关实验视频

Updated: Jul 14, 2025

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications

Published on: August 12, 2013

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在多电离混合化物固态电解质中的通用超级电离子导电性

Xiaona Li1, Yang Xu2,3, Changtai Zhao2

  • 1Eastern Institute for Advanced Study, Eastern Institute of Technology, Ningbo, Zhejiang 315200, P. R. China.

Angewandte Chemie (International ed. in English)
|October 6, 2023
PubMed
概括

研究人员使用多酸混合策略开发了新的固态电解质 (SSEs). 这些UCl3类型的SSE具有高离子导电性,并使稳定的全固态电池 (ASSLB) 具有出色的性能.

关键词:
所有固态电池都是固态电池.化物固体电解质是一种固体电解质.多个阴离子的多重阴离子固态电解质 固态电解质UCl3 结构 结构

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Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature
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Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature

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Dynamic Electrochemical Measurement of Chloride Ions
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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
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Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature
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Dynamic Electrochemical Measurement of Chloride Ions
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科学领域:

  • 材料科学 材料科学 材料科学
  • 电化学 电化学 电化学
  • 固态化学 固态化学

背景情况:

  • 全固态电池 (ASSLBs) 对下一代能源存储充满希望.
  • 先进的固态电解质 (SSEs) 对ASSLB的性能至关重要.

研究的目的:

  • 开发新的UCL3型固态电解质 (SSEs),使用具有成本效益的宿主和多离子混合策略.
  • 调查这些SSE与ASSLBs的高压阴极的离子导电性和兼容性.

主要方法:

  • 使用LaCl和CeCl作为宿主格子的UCL3型SSE的合成.
  • 结合多个金属酸来诱导结构障碍和增强离子运输.
  • 电化学表征包括离子导电量测量和ASSLB原型中的循环稳定性测试.

主要成果:

  • 达到高室温离子导电率超过10-3 S cm-1 .
  • 与高压氧化物阴极具有良好的兼容性.
  • 开发了一个稳定的ASSLB原型,具有3000多个循环和在-30°C的高可逆性.
  • 由于六角通道和无形相,观察到快速的多重离子导电 (Li+,Na+,K+,Cu+,Ag+)

结论:

  • 新型UCL3类型的SSE为开发高性能ASSLB提供了有希望的途径.
  • 多混合策略有效地提高了离子导电性和电池稳定性.
  • 对混合化的进一步研究可能会为高能量密度的ASSLB带来先进的化SSE.