密集的体液体和玻璃中的定向顺序
Yiming Xia1,2, Xiunan Yang1,2, Junchao Huang3
1Beijing National Laboratory for Condensed Matter Physics and Key Laboratory of Soft Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, People's Republic of China.
Physical review letters
|October 6, 2023
概括
结构顺序参数揭示了密集的体悬浮液的关键见解. 当地定向顺序,而不是转换顺序,显著影响玻璃系统中的动态.
科学领域:
- 物理 物理学 物理
- 材料科学 材料科学 材料科学
- 化学 化学 化学
背景情况:
- 了解密集的体悬浮物的动态对于材料科学至关重要.
- 玻璃系统和超冷液体表现出复杂的结构和动态行为.
- 传统方法通常依赖于两体结构来关联结构和动力学.
研究的目的:
- 为密集的合物悬浮物开发新的结构顺序参数.
- 研究地方结构秩序与地方动态之间的关系.
- 为了比较方向顺序与系统动态上的转化顺序的预测能力.
主要方法:
- 使用局部角和半径分布函数构建结构顺序参数.
- 分析这些顺序参数与局部动态之间的相关性.
- 激发模型的应用,以解释结构动力学相关性.
主要成果:
- 所有构造的顺序参数都与超冷和玻璃化系统的局部动态有显著的相关性.
- 定向顺序和动态异质性之间的相关性比结构的相关性更强.
- 激发模型成功地解释了结构动力学相关性,而能量障碍取决于局部结构秩序.
结论:
- 在密集的无序包装中,局部定向顺序比翻译顺序更为重要.
- 定向顺序在确定玻璃系统的动态方面发挥着主导作用.
- 开发的顺序参数更准确地描述了合玻璃中的结构动力学关系.
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