使用线性ATR-FTIR和拉曼光谱仪量化密集的多元件泥:汉福德的案例研究
Rupanjali Prasad1, Steven H Crouse1, Ronald W Rousseau1
1School of Chemical and Biomolecular Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332, United States.
概括
拉曼和减弱总反射率-里埃变换红外光谱 (ATR-FTIR) 提供了更安全,更快的核废物泥线上分析. 这些方法为有效的废物处理和处置提供了关键的组成数据.
科学领域:
- 分析化学 分析化学
- 频谱学是一种光谱学.
- 核废物管理 核废物管理
背景情况:
- 核废物泥,如汉福德的泥,是复杂的多相混合物.
- 目前基于实验室的分析速度很慢,对工人构成风险.
- 为了高效的处理,需要实时的在线监控.
研究的目的:
- 评估拉曼和ATR-FTIR光谱法用于分析核废物泥模拟剂.
- 确定每个溶液和固态分析技术的有效性.
- 建立直线光谱方法作为传统实验室分析的可行替代方案.
主要方法:
- 在泥模拟剂上测试拉曼光谱.
- 在泥模拟剂上测试减弱总反射率-里埃变换红外光谱 (ATR-FTIR).
- 分析含有高达23.2重 %固体物质的泥.
主要成果:
- 通过ATR-FTIR光谱仪准确地测量了溶液阶段 (3.52%的平均误差).
- 拉曼光谱学提供了悬浮固体 (18.21%的平均误差) 的信息.
- 核废物中多元件固体的直线测量以前没有报告.
结论:
- 拉曼光谱和ATR-FTIR光谱都有效用于核废物泥的线性分析.
- 这些光谱方法为组合分析提供了更安全,更快的替代方案.
- 准确的成分数据对于稳定的玻璃配方和核废物处理至关重要.
相关概念视频
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