相关实验视频
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Research and Development of High-performance Explosives
Published on: February 20, 2016
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一种三维能量协调化合物 (BLG-1),具有无初级爆炸物的优良启动能力
Guorong Lei1, Wenchuan Cheng1, Zujia Lu1
1State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China. lizm@bit.edu.cn.
Materials horizons
|October 9, 2023
概括
合成了一种新的无能量协调化合物BLG-1. 这种富含N的铜酸盐表现出卓越的启动功率和热稳定性,为以为基础的初级爆炸物提供了有希望的替代品.
科学领域:
- 能量材料科学 能量材料科学
- 协调化学 协调化学
- 材料合成 材料合成
背景情况:
- 由于安全和环境原因,开发先进的无初级爆炸物至关重要.
- 现有的以为基础的初级爆炸物具有显著的毒性风险.
- 需要高性能,对环境无害的能量材料.
研究的目的:
- 设计和合成一种新的富含N的铜酸盐能量协调化合物 (ECC).
- 研究合成化合物的结构性,热性和启动性.
- 评估其作为无初级爆炸物的潜力.
主要方法:
- 为了合成富含N的铜酸盐ECC,采用了简单的一步反应,标记为BLG-1.
- 进行了结构性表征,以确认三维 (3D) 网状结构.
- 性能评估包括RDX和CL-20的引爆测试,以及测量热分解温度,晶体密度和灵敏度 (冲击,摩擦,静电,激光).
主要成果:
- 首个报告的3D N丰富的铜酸盐ECC,BLG-1 ([Cu(ATRZ) ((BrO3) 2),已成功合成.
- BLG-1在同类中表现出最高的热分解温度 (226°C) 和晶体密度 (2.69gcm-3) .
- 它表现出超强的启动能力,引爆了3毫克的压缩RDX和1毫克的CL-20,超过了之前报告的初级爆炸物.
- 与酸相比,观察到更好的机械和静电敏感性,具有特别低的激光启动值 (13mJ在808nm).
结论:
- BLG-1是一种非常有前途的无初级爆炸物候选物.
- 它独特的3D结构有助于其卓越的热稳定性和启动性能.
- BLG-1为各种应用提供了一个更安全,更有效的替代传统的以为基础的初级爆炸物.
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