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相关概念视频

Precipitation of Ions03:11

Precipitation of Ions

28.0K
Predicting Precipitation
The equation that describes the equilibrium between solid calcium carbonate and its solvated ions is:
28.0K
Ionic Bonding and Electron Transfer02:48

Ionic Bonding and Electron Transfer

41.7K
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions. 
41.7K
Solubility of Ionic Compounds02:55

Solubility of Ionic Compounds

63.3K
Solubility is the measure of the maximum amount of solute that can be dissolved in a given quantity of solvent at a given temperature and pressure. Solubility is usually measured in molarity (M) or moles per liter (mol/L). A compound is termed soluble if it dissolves in water.
63.3K
Trends in Lattice Energy: Ion Size and Charge02:54

Trends in Lattice Energy: Ion Size and Charge

24.0K
An ionic compound is stable because of the electrostatic attraction between its positive and negative ions. The lattice energy of a compound is a measure of the strength of this attraction. The lattice energy (ΔHlattice) of an ionic compound is defined as the energy required to separate one mole of the solid into its component gaseous ions. For the ionic solid sodium chloride, the lattice energy is the enthalpy change of the process:
24.0K
Ionic Strength: Effects on Chemical Equilibria01:19

Ionic Strength: Effects on Chemical Equilibria

1.5K
The addition of an inert ionic compound increases the solubility of a sparingly soluble salt. For example, adding potassium nitrate to a saturated solution of calcium sulfate significantly enhances the solubility of calcium sulfate. Le Châtelier's principle cannot predict this shift in the equilibrium. Instead, this could be explained in terms of changes in the effective concentration of the ions in solution in the presence of added inert salt.
In this solution, the primary...
1.5K
Intermolecular Forces03:13

Intermolecular Forces

58.6K
Atoms and molecules interact through bonds (or forces): intramolecular and intermolecular. The forces are electrostatic as they arise from interactions (attractive or repulsive) between charged species (permanent, partial, or temporary charges) and exist with varying strengths between ions, polar, nonpolar, and neutral molecules. The different types of intermolecular forces are ion–dipole, dipole–dipole, hydrogen bonds, and dispersion; among these, dipole–dipole, hydrogen...
58.6K

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相关实验视频

Updated: Jul 14, 2025

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
06:44

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding

Published on: March 24, 2018

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在LiO2电解质中依赖溶剂的化物相互作用 - 一个分子动力学研究研究.

Erlendur Jónsson1, Astrid H Berge1, Clare P Grey1

  • 1Yusuf Hamied Department of Chemistry, University of Cambridge, UK. ej311@cam.ac.uk.

Faraday discussions
|October 9, 2023
PubMed
概括

电解质组成会影响酸基氧电池的性能. 较短的糖质和特定的水度优化 (I-) 溶解和离子 (Li+) 相互作用,以提高效率.

科学领域:

  • 电化学 电化学 电化学
  • 材料科学 材料科学 材料科学
  • 计算化学计算化学

背景情况:

  • 基于的氧化还原介质在氧 (Li-O2) 电池中提供了高的往返效率.
  • 离子 (I-) 的溶解对于高效的氧化还原调解至关重要.

研究的目的:

  • 研究电解质组成对化物 (I-) 溶解在Li-O2电池中的影响.
  • 了解甘氨酸链长度和水含量如何影响离子相互作用.

主要方法:

  • 使用了分子动力学模拟.
  • 化物 (I-),水 (H2O) 和离子 (Li+) 度在甘中 (G1-G4) 的组合勘探.

主要成果:

  • 较短的糖体促进化 (I-) 氧化还原介质的更紧密的包装.
  • 化物 (I-) 度增加会降低离子 (Li+) 溶解,特别是在G2.
  • 添加水可增强化物 (I-) 和离子 (Li+) 之间的相互作用,在较短的糖体中效果更大.

结论:

  • 电解质成分,特别是甘氨酸链长度和含水量,显著调节离子溶解和相互作用.
  • 优化电解质配方是提高酸介导Li-O2电池性能的关键.

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