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Catalysis02:50

Catalysis

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The presence of a catalyst affects the rate of a chemical reaction. A catalyst is a substance that can increase the reaction rate without being consumed during the process. A basic comprehension of a catalysts’ role during chemical reactions can be understood from the concept of reaction mechanisms and energy diagrams.
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Reduction of Alkenes: Asymmetric Catalytic Hydrogenation02:17

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Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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Reduction of Alkenes: Catalytic Hydrogenation02:13

Reduction of Alkenes: Catalytic Hydrogenation

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Alkenes undergo reduction by the addition of molecular hydrogen to give alkanes. Because the process generally occurs in the presence of a transition-metal catalyst, the reaction is called catalytic hydrogenation.
Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
The hydrogenation process takes place on the...
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Introduction to Mechanisms of Enzyme Catalysis01:13

Introduction to Mechanisms of Enzyme Catalysis

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For many years, scientists thought that enzyme-substrate binding took place in a simple "lock-and-key" fashion. This model stated that the enzyme and substrate fit together perfectly in one instantaneous step. However, current research supports a more refined view scientists call induced fit. The induced-fit model expands upon the lock-and-key model by describing a more dynamic interaction between enzyme and substrate. As the enzyme and substrate come together, their interaction causes...
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Reduction of Alkynes to cis-Alkenes: Catalytic Hydrogenation02:24

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Introduction
Like alkenes, alkynes can be reduced to alkanes in the presence of transition metal catalysts such as Pt, Pd, or Ni. The reaction involves two sequential syn additions of hydrogen via a cis-alkene intermediate.
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Unlike the easy catalytic hydrogenation of an alkene double bond, hydrogenation of a benzene double bond under similar reaction conditions does not take place easily. For example, in the reduction of stilbene, the benzene ring remains unaffected while the alkene bond gets reduced. Hydrogenation of an alkene double bond is exothermic and a favorable process. In contrast, to hydrogenate the first unsaturated bond of benzene, an energy input is needed; that is, the process is endothermic. This is...
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Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks MOFs
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异质单个集群催化学的进展.

Xinzhe Li1,2, Sharon Mitchell3, Yiyun Fang2

  • 1Department of Environmental Science and Engineering, School of Energy and Power Engineering, Xi'an Jiaotong University, Xi'an, Shaanxi, China.

Nature reviews. Chemistry
|October 9, 2023
PubMed
概括

单集群催化剂 (SCC) 为新型反应提供可调节的特性. 了解集群环境是释放异质催化中的稳定和选择性性能的关键.

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科学领域:

  • 催化剂是一种催化剂.
  • 材料科学 材料科学 材料科学
  • 表面化学 表面化学

背景情况:

  • 单催化剂 (SCC) 具有原子精确的金属在支上,显示出新反应的前景.
  • 过去的研究面临着合成和分析方面的挑战,限制了对表面化学的理解.
  • 集群环境对SCC业绩产生重大影响.

研究的目的:

  • 突出SCC中集群环境的重要性.
  • 为了证明如何定制整个催化组合可以提高性能.
  • 探索SCC设计的未来方向.

主要方法:

  • 对SCCs现有文献的审查.
  • 分析影响SCC性能的因素:金属支相互作用,联体球,反应介质和动力学.
  • 为各种反应量身定制的SCC的说明性示例.

主要成果:

  • 强大的金属支相互作用和受控的连接体球是至关重要的.
  • 反应介质和动态集群行为影响反应性.
  • 定制整个催化组合可以实现稳定和选择性催化.

结论:

  • 考虑完整的集群环境对于推进SCCs至关重要.
  • 在复杂反应中,SCC可以被设计为稳定和选择性性能.
  • 对SCC设计的进一步研究对催化有很大的潜力.