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Updated: Jul 14, 2025

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一个以乙烯基改性互穿金属有机框架,用于高效的选择性气体吸附

Xueyue Yu1, Ziyang Huang2, Rajamani Krishna3

  • 1State Key Laboratory of Inorganic Synthesis & Preparative Chemistry, Jilin University, Changchun 130012, P. R. China. yunling@jlu.edu.cn.

Dalton transactions (Cambridge, England : 2003)
|October 10, 2023
PubMed
概括

合成了一种具有罕见的lvt拓的新型乙烯基改性金属有机框架 (MOF). 这种相互透的MOF表现出增强的稳定性和优越的气体吸附能力,显示了气体分离应用的潜力.

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Olefin Metathesis Polymerization: Acyclic Diene Metathesis (ADMET)00:53

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Acyclic diene metathesis polymerization or ADMET polymerization involves cross-metathesis of terminal dienes, such as 1,8-nonadiene, to give linear unsaturated polymer and ethylene. As ADMET is a reversible process, the formed ethylene gas must be removed from the reaction mixture to complete the polymerization process.
Similar to cross-metathesis, ADMET also involves the formation of metallacyclobutane intermediate by [2+2] cycloaddition of one of the double bonds of a terminal diene with...
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