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碳氧甲基纤维素在纤维素上的阳离子特定吸附
Vishnu Arumughan1,2, Hüsamettin Deniz Özeren3, Mikael Hedenqvist3,4,5
1Department of Chemistry and Chemical Engineering, Chalmers University of Technology, SE-41296 Gothenburg, Sweden.
Langmuir : the ACS journal of surfaces and colloids
|October 11, 2023
概括
阴离子类型显著影响碳素甲基纤维素 (CMC) 吸附在纤维素上,随着酸盐等杂热性阴离子比大热性硫酸盐更多地增强吸附. 这一发现对于纸厂的功能性纤维生产至关重要.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 表面化学 表面化学
背景情况:
- 将纤维修饰集成到纸厂中,为功能性纤维生产提供了资源效率.
- 了解聚合物吸附,特别是甲基纤维素 (CMC),是优化这种整合的关键.
研究的目的:
- 为了研究阴离子对碳氧甲基纤维素 (CMC) 吸附在纤维素表面的特定影响.
- 为了将CMC吸附与盐中的共离子的水合特性相关联.
主要方法:
- 用于吸附实验的石晶体微平衡与散射监测 (QCM-D).
- 使用纤维素模型表面研究CMC吸附动态.
- 研究了不同盐 (酸盐与硫酸盐) 对CMC吸附的影响.
主要成果:
- 对纤维素的CMC吸附对离子特异性影响敏感.
- 相比于大热离子 (例如硫酸盐),热离子 (例如酸盐) 显著增加了CMC吸附.
- 与酸相比,酸的阴离子特异性不那么明显.与酸相比.
结论:
- 阳离子水化程度会影响CMC吸附,更多的水化阳离子 (无otropic) 会促进更大的吸附.
- 在纤维素-水界面的阳离子分布,由水化驱动,影响水的排序和,从而调节CMC吸附.
- 结果为定制纸厂工艺提供了洞察力,以提高功能性纤维生产.
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