流体四二的基本状态方程
Felix Fiedler1, Joel Karog1, Eric W Lemmon2
1Lehrstuhl für Thermodynamik, Ruhr-Universität Bochum, Universitätsstraße 150, 44801 Bochum, Germany.
概括
一个新的四基的状态方程准确地预测了各种阶段和条件的热力学特性. 这种基于大量数据的模型为密度,声音速度和热容量提供了高精度.
科学领域:
- 热力学是一种热力学.
- 物理化学 物理化学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 准确的热力学性能数据对于化学过程设计和安全至关重要.
- 对于四二的现有状态方程可能缺乏全面的覆盖或精确性.
- 甲基是化学合成和工业应用中广泛使用的溶剂.
研究的目的:
- 开发一个精确可靠的实证基本方程状态为四.
- 覆盖广泛的温度 (三点到550K) 和压力 (高达600MPa) 范围.
- 为了能够计算液体,蒸汽和超临界区域的所有热力学特性,包括和状态.
主要方法:
- 基于赫尔姆霍尔茨能量公式的实证状态方程的开发.
- 广泛的文献审查,以收集和批判性地评估实验数据.
- 实验数据在其固有的不确定性中的表示.
主要成果:
- 状态方程准确地表示了四水夫的实验数据.
- 在大气压下,密度 (0.015%),声速 (0.03%) 和同体热容量 (0.4%在液相) 的不确定性是可以实现的.
- 蒸汽压力以不确定性计算,不确定性在0.02%至3%之间,取决于温度.
- 观察到对极端条件的合理推断行为.
结论:
- 呈现的状态方程为计算四二的热力学特性提供了可靠的工具.
- 模型的准确性通过其与实验数据的密切一致而得到验证.
- 这项工作有助于改进涉及四二的过程建模和优化.
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