从酸胺 (SQAs) 到素基SQAs――有机聚合物电池的反氧活性阴极材料的演变
Marcel E Baumert1, Victoria Le2, Po-Hua Su3,4
1Faculty of Chemistry and Chemical Biology (CCB), Technical University Dortmund, Otto-Hahn-Str. 6, D-44227 Dortmund, Germany.
Journal of the American Chemical Society
|October 12, 2023
概括
我们开发了新的酸素 (SQXs) 作为稳定,高潜在的氧化还原活性有机物质, 基于SQX的聚合物具有出色的热稳定性和可逆的氧化还原特性,可实现100多个稳定的充放电周期.
科学领域:
- 材料科学
- 电化学
- 有机化学
背景情况:
- 可持续的储能需要先进的氧化还原活性有机材料 (ROM).
- 之前的酸胺 (SQAs) 在基离子状态下缺乏稳定性.
- 实际应用需要一个强大的两电子还氧化系统.
研究的目的:
- 作为稳定的ROM,引入一个新类型的cyclobuta[b]quinoxaline-1,2-diones (SQX).
- 合成和描述SQX化合物及其基离子.
- 开发和评估用于储能的SQX功能化的聚合物.
主要方法:
- 合成和描述SQX化合物和基离子.
- 电化学分析,包括循环电压测量.
- 光谱技术 (EPR,UV-vis) 和X射线衍射.
- 基于SQX聚合物的离子半电池的制造和测试.
主要成果:
- SQX表现出特殊的稳定性和高的氧化还原潜力.
- SQX聚合物具有很高的热稳定性 (> 200 °C) 和可逆的氧化还原行为.
- 聚合物达到约3.6V的氧化还原潜力与Li+/Li.
- 一种基于烯的SQX聚合物显示稳定循环超过100个循环.
结论:
- SQXs代表了一个非常有前途的新类强大的氧化还原活性有机材料.
- 具有SQX功能的聚合物为储能提供了卓越的稳定性和电化学性能.
- 这项工作为可持续能源解决方案中的先进有机材料铺平了道路.
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