在分层的2D纳米填充剂基聚合物介电膜中超高容量能量密度
Maninderjeet Singh1, Priyanka Das2, Pabitra Narayan Samanta2
1Department of Chemical & Biomolecular Engineering, University of Houston, Houston, Texas 77204, United States.
ACS nano
|October 13, 2023
概括
研究人员使用2D纳米填充剂开发了一种新的聚合物薄膜电容器. 这种材料实现了超高的能量密度 (75 J/cm3) 和高效率,推进了聚合物介电电容器用于储能.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物科学 聚合物科学
- 纳米技术 纳米技术
背景情况:
- 介电电容器对于电子和储能至关重要.
- 聚合物电容提供灵活性和快速充放电,但对于电动汽车 (EV) 等应用需要更高的能量密度.
研究的目的:
- 为了提高聚合物介电电容器的能量密度.
- 开发一种用于制造高性能薄膜电容器的多功能方法.
主要方法:
- 使用聚乙烯化物 (PVDF) 和聚甲基酸 (PMMA) 制造聚合物薄膜异构结构.
- 纳入分层的2D纳米填充剂 (米卡或六边形化纳米板).
- 介电性质和能量密度的表征.
- 密度函数理论 (DFT) 计算来验证允许度增强.
主要成果:
- 实现了大约75 J/cm3的超高能量密度.
- 证明了增强的电容性和高介电强度.
- 实现了超过79%的能量转换效率.
结论:
- 开发的聚合物薄膜异构结构与定向的2D纳米填充剂显著提高了能量密度.
- 这种复合材料对设计先进的高能量密度薄膜聚合物介电电容器具有很大的前景.
- 这种方法适用于各种苛刻的应用程序.
相关概念视频
Dielectric Polarization in a Capacitor
4.7K
The presence of a dielectric medium in a capacitor not only changes the voltage and capacitance but also affects the electric field. In general, dielectrics can be of two types: polar and nonpolar. In a polar dielectric, the positive and negative charges in the molecules are separated by a distance and hence have a permanent dipole moment. In contrast, no such charge separation exists in a nonpolar dielectric, however the nonpolar molecules get polarized in the presence of an external electric...
4.7K
Potential Due to a Polarized Object
419
A neutral atom consists of a positively charged nucleus surrounded by a negatively charged electron cloud. When placed in an external electric field, the external electric force pulls the electrons and nucleus apart, opposite to the intrinsic attraction between the nucleus and the electrons. The opposing forces balance each other with a slight shift between the center of masses of the nucleus and the electron cloud, resulting in a polarized atom. On the other hand, a few molecules, like water,...
419
Capacitor With A Dielectric
4.0K
Parallel plate capacitors consist of two conducting plates separated by a certain distance. However, it is mechanically difficult to hold the large plates parallel to each other without actual contact. Hence, a dielectric layer is commonly placed between the plates, which provides an easy solution for holding the plates together with a small gap and increases the capacitance of the capacitor.
Dielectrics are non-conducting materials with no free or loosely bound electrons. When a dielectric is...
Dielectrics are non-conducting materials with no free or loosely bound electrons. When a dielectric is...
4.0K
Susceptibility, Permittivity and Dielectric Constant
1.6K
When placed in an external electric field, a dielectric material gets polarized. The charge density in the dielectric material is given by the sum of the bound and free charge densities, while the total charge density can also be written in terms of the total electric field. The bound charge density can be measured in terms of polarization, leading to the relationship between electric displacement and polarization.
1.6K
Gauss's Law in Dielectrics
4.4K
Consider a polar dielectric placed in an external field. In such a dielectric, opposite charges on adjacent dipoles neutralize each other, such that the net charge within the dielectric is zero. When a polar dielectric is inserted in between the capacitor plates, an electric field is generated due to the presence of net charges near the edge of the dielectric and the metal plates interface. Since the external electrical field merely aligns the dipoles, the dielectric as a whole is neutral. An...
4.4K


