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Updated: Jul 13, 2025

[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
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通过素基基离子对激素的同解C-H键激活

Christoph Helling1, Lars J C van der Zee1, Jelle Hofman1

  • 1Van't Hoff Institute for Molecular Sciences, University of Amsterdam, PO Box 94157, 1090, GD Amsterdam, The Netherlands.

Angewandte Chemie (International ed. in English)
|October 13, 2023
PubMed
概括

这项研究揭示了在氨酸-氨酸系统中由单电子转移形成的短暂基离子对如何激活C-H键. 这些基离子对为C-H键功能化提供了一条新的途径.

关键词:
C−H 激活方式丧的易斯对 丧的易斯对激进的离子对对.激进分子 激进分子单个电子转移是单个电子转移.

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