基酸 (HT) 衍生Cu催化剂用于催化转化生物乙醇为butanol
1Hangzhou Institute of Advanced Studies, Zhejiang Normal University, 1108 Gengwen Road, Hangzhou 311231, China.
由基酸衍生的支持铜催化剂通过Guerbet合有效地将乙醇转化为n-butanol. /NiAlOx表现出卓越的稳定性和选择性,突出了支持可降解性和酸性质对生物质价值化的重要性.
科学领域:
- 催化剂是一种催化剂.
- 材料科学 材料科学 材料科学
- 绿色化学 绿色化学
背景情况:
- 生物质的利用对于可持续的化学品生产至关重要.
- 甲醇与n-butanol的Guerbet合是转化生物质原料的关键反应.
- 开发稳定和选择性的催化剂对于这一过程至关重要.
研究的目的:
- 准备和评估支持的Cu催化剂,由Ni基酸 (HT) 衍生而成,用于乙醇转化为n-butanol.
- 研究不同金属氧化物支 (NiAlOx,NiFeOx,NiCoOx) 对催化剂性能的影响.
- 了解禁用机制,并确定催化剂稳定性和选择性的关键因素.
主要方法:
- 支持Cu催化剂的合成,使用基于Ni的酸前体.
- 在280°C下对乙醇转化为n-butanol的连续流催化试验.
- 使用XRD,TEM,XPS和H2-TPR的新鲜和耗尽的催化剂的表征.
主要成果:
- /NiAlOx表现出最佳性能,在流动110小时内实现约35%的乙醇转化和25%的butanol选择性.
- /NiFeOx和/NiCoOx催化剂显示出非活化和/或较低的butanol选择性.
- 催化剂失活主要归因于支持解构,与可还原性相关,而酸性质则影响了选择性.
结论:
- Cu/NiAlOx 是一个有前途的催化剂,用于不断地将乙醇转化为n-butanol.
- 支持可降解性和适当的酸性质对于催化剂稳定性和提高格尔贝合中的布他诺选择性至关重要.
- 了解禁用机制对于设计可靠的生物质价值化催化剂至关重要.
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