在带有活性碳电极的对称超级电容器中的自放电过程
Alexey Yu Rychagov1, Valentin E Sosenkin1, Marianna Yu Izmailova1
1A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninsky Pr. 31, 119071 Moscow, Russia.
Materials (Basel, Switzerland)
|October 14, 2023
概括
带有活性碳电极的电双层电容器 (EDLC) 中的自放电受电压的影响. 电极之间的电荷转移驱动自放电,在1.4V的最佳稳定50分钟.
科学领域:
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 电双层电容器 (EDLC) 对于储能至关重要.
- 了解EDLC中的自放电机制对于性能优化至关重要.
- 复合活性碳电极和水性电解质具有独特的电化学行为.
研究的目的:
- 用复合活性炭电极和水性硫酸电解液来研究EDLC的自放电特性.
- 确定控制自放电过程的关键因素和阶段.
- 确定最大限度地减少自放电的最佳条件.
主要方法:
- 对EDLC进行了潜在静电电荷 (稳定) 实验.
- 随着时间的推移,测量了放电容量,以量化自放电.
- 进行了电极表面分析,以了解材料变化.
主要成果:
- 观察到自放电在0.8V以上的电压下显著增加.
- 自放电过程有两个不同的阶段:初始电荷再分配和主电荷转移.
- 最佳稳定条件被确定为50分钟的1.4V.
- 长期的极化导致负电极的水友性,这是由于环氧功能组的形成.
结论:
- 水性EDLC的自放电取决于电压,并涉及不同的电荷转移机制.
- 特定的稳定协议可以减轻自放电损失.
- 电极表面的修改,如水友性,可以影响EDLC在操作期间的性能.
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