CoRE2W2O10陶材料的磁性和电气特性2 W2O10陶材料的磁性和电气性能2 W2O10 陶材料的磁性和电气性能10 陶材料的磁性和电气性能
Bogdan Sawicki1, Elżbieta Tomaszewicz2, Tadeusz Groń1
1Institute of Physics, University of Silesia in Katowice, 40-007 Katowice, Poland.
ACS omega
|October 16, 2023
概括
研究人员合成了CoRE2W2O10酸盐,揭示了单临床结构和低导电性. 阳离子空位和离子价值状态驱动这些有前途的热电材料中的电子运输.
科学领域:
- 固态化学和材料科学 固态化学和材料科学
- 探索稀土酸化合物.
背景情况:
- Tungstate 材料具有独特的磁性和电性.
- 了解电荷传输机制对于热电应用至关重要.
研究的目的:
- 为了合成和描述CoRE2W2O10酸盐 (RE = Y,Dy,Ho,Er).
- 研究它们的结构性,磁性,电性和热电性质.
- 阐明控制电子传输的机制.
主要方法:
- 用于样品制备的高温固态反应.
- 陶烧结用于增强性能.
- 综合性表征包括结构,显微,紫外线,磁,电和热电测量.
主要成果:
- 在所有样本中确认了单临床结构.
- 观察到对磁性,具有短距离的抗铁磁和长距离的铁磁相互作用 (在CoY2W2O10中).
- 较差的n型导电性 (6.7 × 10−7 S/m),强烈的热激活 (Ea1 = 0.7 eV),以及超过300 K的显著功率因子增加.
结论:
- 阳离子空位水平作为主要电子捐赠者.
- 混合价值离子 (Co2+,Co3+) 也有助于电子传输.
- 这些发现突显了热电应用的潜力.
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