二元合体的刚性诱导控制聚合
Zakiya Shireen1, Tine Curk2, Christian Brandl1
1Department of Mechanical Engineering, Faculty of Engineering and Information Technology, University of Melbourne, 3010 Parkville, Victoria Australia.
ACS omega
|October 16, 2023
概括
在二元合体系统中通过调整键的灵活性来实现受控聚合. 结合的刚性会影响两种物种的凝形成,临界度和聚合动力学.
科学领域:
- 合体和表面科学科学
- 材料科学是一种材料科学.
- 软物质物理学 软物质物理学
背景情况:
- 在材料科学和生物过程中,体系统是基本的.
- 了解聚合动力学对于控制材料特性至关重要.
- 二元合体系统提供复杂的相互作用动态.
研究的目的:
- 在二元合体系统中展示受控聚合.
- 调查债券灵活性和刚性的对聚合的影响.
- 为了确定凝和结合特性之间的关系.
主要方法:
- 研究一种物种中具有不同结合灵活性的二元合体系统.
- 分析结合灵活性,临界度和包装体积分数的相互作用.
- 使用绑定邻居分析的平均数量.
主要成果:
- 键的刚性增加了二元混合物中凝形成的临界度.
- 键的刚性会影响聚合动力学,无论是在临界度以上还是以下.
- 一种物种的灵活性变化会改变两种物种的聚合动力学.
结论:
- 通过调整键的灵活性,可以在二元合体系统中实现受控聚合.
- 结合的刚性在决定凝和聚合动态方面发挥着重要作用.
- 这项研究增强了对软体和生物环境中的体聚合的理解.
相关概念视频
Colloidal precipitates
596
The high insolubility of some precipitates can result in an unfavorable relative supersaturation. This can lead to colloidal particles with a large surface-to-mass ratio, where adsorption is promoted. For instance, in the precipitation of silver chloride, silver ions are adsorbed on the surface of the colloidal particles, forming a primary layer. This layer attracts ions of opposite charge (such as nitrate ions), forming a diffuse secondary layer of adsorbed ions. This electric double layer...
596
Coagulation
315
Colloidal solids are solid particles suspended in solution. They are usually negatively charged, attracting a compact primary layer of positively charged ions, which attract more counterions to form an electrical double layer. Electrostatic repulsion between the charged double layers prevents the particles from colliding, stabilizing the colloids. These solids are often undesirable because they can contain toxins that are difficult to remove. Coagulation is a technique that helps aggregate and...
315
Colloids
17.6K
Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles that are visible to the naked eye or can be seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. On the other hand, a solution is a homogeneous mixture in which no settling occurs and in which the dissolved...
17.6K
Colloids and Suspensions
1.8K
Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles visible to the naked eye or seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. The suspended particles in a suspension settle out after some time of mixing. The separation of particles from a suspension is...
1.8K
Mechanism of Filopodia Formation
2.4K
Filopodia are thin, actin-rich cellular protrusions that play an important role in many fundamental cellular functions. They vary in their occurrence, length, and positioning in different cell types, suggesting their diverse roles.
Their main function is to guide migrating cells during normal tissue morphogenesis or cancer metastasis by recognizing and making initial contacts with the extracellular matrix. However, they can also act as stationary cell anchors or help to establish communication...
Their main function is to guide migrating cells during normal tissue morphogenesis or cancer metastasis by recognizing and making initial contacts with the extracellular matrix. However, they can also act as stationary cell anchors or help to establish communication...
2.4K
Precipitate Formation and Particle Size Control
793
In precipitation gravimetry, the precipitating agent should react specifically or selectively with the analyte. While a specific reagent reacts with the analyte alone, a selective reagent can react with a limited number of chemical species.
The obtained precipitate should be either a pure substance of known composition or easily converted to one by a simple process, such as ignition or drying. In addition, the precipitate should be insoluble and easily filterable. In general, filterability...
The obtained precipitate should be either a pure substance of known composition or easily converted to one by a simple process, such as ignition or drying. In addition, the precipitate should be insoluble and easily filterable. In general, filterability...
793


