在压力下的深超冷水中,粘度和斯托克斯-爱因斯坦关系
Alexandre Mussa1, Romain Berthelard1, Frédéric Caupin1
1Institut Lumière Matière, Université de Lyon, Université Claude Bernard Lyon 1, CNRS, Institut Universitaire de France, F-69622 Villeurbanne, France.
The Journal of chemical physics
|October 17, 2023
概括
研究人员在高压和低温下测量了水的粘度,揭示了非Arrhenius行为和压力诱导的粘度下降. 这表明水中存在潜在的液体-液体临界点.
科学领域:
- 物理化学 物理化学
- 热力学是一种热力学.
- 流体动力学 流体动力学
背景情况:
- 在极端条件下,水表现出复杂的行为.
- 了解水的特性对于各种科学学科至关重要.
研究的目的:
- 用于在高压 (高达150MPa) 和低温 (低至229.5K) 的水中测量剪切粘度 (η).
- 为了研究水的粘度的温度和压力依赖.
- 在超冷水中检查斯托克斯-爱因斯坦关系的有效性.
主要方法:
- 在水中测量剪切粘度 (η) 的实验测量.
- 对温度和压力依赖性的数据分析.
- 与文献数据进行自我扩散系数 (Ds) 的比较.
主要成果:
- 在所有压力下观察到的粘度的非阿雷尼乌斯温度依赖性.
- 与20MPa以上的压力相比,在0.1MPa时的温度依赖性质上有所不同.
- 非单调的压力依赖性,在低温下粘度下降>50%.
- 观察到Dsη/T的温度和压力依赖,类似于对现实的水模型的模拟.
结论:
- 水的粘度在高压和低温下表现出复杂的行为.
- 斯托克斯-爱因斯坦关系在超冷水中的行为与模拟相一致.
- 结果表明,在正压下与水中的液体-液体临界点相兼容.
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