硬球的光热结晶在一个有效的二维几何学
Vincenzo Ruzzi1, Jacopo Baglioni1, Roberto Piazza1
1Department of Chemistry, Materials Science, and Chemical Engineering (CMIC) "Giulio Natta," Politecnico di Milano, Edificio 6, Piazza Leonardo da Vinci 32, 20133 Milano, Italy.
The Journal of chemical physics
|October 18, 2023
概括
热友性合体在激光加热时形成有序的晶体. 由热泳驱动的粒子运动导致了没有典型的两阶段核形成的均晶体生长.
科学领域:
- 体科学是关于体的科学.
- 软物质物理学 软物质物理学
- 结晶的动态 结晶的动态
背景情况:
- 体粒子的二维限制对于研究相位过渡至关重要.
- 热泳驱动粒子运动,以应对局部温度梯度.
- 了解核和生长机制是控制物质结构的关键.
研究的目的:
- 研究局部加热诱导的合晶体的核和生长.
- 分析热泳在粒子聚合和排序中的作用.
- 描述形成的晶体的结构性质.
主要方法:
- 在一个二维单元中将合物颗粒封闭起来.
- 使用近红外激光来产生局部加热并诱导热泳.
- 监控集群结构,使用命令参数进行局部密度和定向排序.
主要成果:
- 粒子形成由热泳驱动的密集集群,没有对流.
- 结晶发生在密度低于硬盘平衡流体极限的密度.
- 没有证据表明玻璃或多态结构的两个阶段核形成.
- 晚期晶体表现出高均性和最小的缺陷,由于界面上的粒子动态.
结论:
- 局部激光加热和热泳为控制的体结晶提供了一种方法.
- 观察到的结晶机制不同于传统的两阶段核化途径.
- 水晶边缘的"流化"可能会导致超稳定的结构,类似于物理蒸气沉积.
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