持久的微量有机污染物在自然基础的地下水处理系统中,在硫酸盐和铁降低条件下迅速转化
Angela N Stiegler1,2, Aidan R Cecchetti1,2, Rachel C Scholes1,2
1Department of Civil & Environmental Engineering, University of California, Berkeley Berkeley, California 94720, United States.
Environmental science & technology
|October 19, 2023
概括
地下处理系统有效地从废水中去除微量有机污染物,主要是通过转化. 设计这些系统以减少硫酸盐和Fe (III) 的条件来增强持续污染物的去除.
科学领域:
- 环境工程 环境工程
- 水处理技术水处理技术
- 环境化学环境化学
背景情况:
- 像建筑湿地一样,地下处理系统 (STS) 是一种低成本的解决方案,用于从城市废水中去除微量有机污染物 (TOC).
- 了解STS中TOC的移除机制对于优化其性能至关重要.
研究的目的:
- 研究在水平堤地下流动湿地中负责TOC去除的转化过程.
- 评估氧化还原条件对可生物降解和持久TOCs的去除的影响.
主要方法:
- 在孔水,沉积物和植物中测量了药品和代谢物的度.
- 进行质量平衡计算,分析转换产物,并进行微观宇宙实验.
- 利用一维运输建模,在不同酸盐条件下监测系统性能.
主要成果:
- 在湿地内的流道上,TOC度迅速下降.
- 超过60%的TOC删除归因于转化过程.
- 可生物降解的TOC在有氧和无氧条件下被去除,而持久的TOC需要Fe (III) 和硫酸盐降解条件来去除.
结论:
- 地下处理系统可以通过转化实现显著的TOC去除.
- 优化氧化还原条件,特别是促进硫酸盐和Fe (III) 减少,是消除持久TOCs的关键.
- 通过受控的转换过程,STS可以被设计成有效地去除各种TOC.
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