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Updated: Jul 12, 2025

Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
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Published on: February 15, 2016

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在三化键中蓝移:在四键和立体排斥之间进行权衡

Lucas de Azevedo Santos1, Storm van der Voort1, Shiri R Burema1

  • 1Department of Chemistry and Pharmaceutical Sciences, AIMMS, Vrije Universiteit, Amsterdam, De Boelelaan 1108, 1081 HZ Amsterdam, The Netherlands.

Chemphyschem : a European journal of chemical physics and physical chemistry
|October 21, 2023
PubMed
概括

量子化学揭示,与结合的复合体中非典型的H-C键蓝变是由于直接的阴离子-碳相互作用而产生的,即四键. 这种相互作用,而不是H-C键的收缩,解释了观察到的频率转移.

关键词:
债券理论 债券理论密度函数计算的密度函数计算能量分解分析分析.通过键结合,可以产生键.非共价相互作用 非共价相互作用

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