三甲基基化合物用于全固态电池中基于酸盐的固体电解质的界面稳定
Kanghyeon Kim1, Taehun Kim1, Gawon Song1
1School of Chemical and Biological Engineering, Institute of Chemical Processes, Seoul National University, 1 Gwanak-ro, Gwanak-gu, Seoul, 08826, Republic of Korea.
Advanced science (Weinheim, Baden-Wurttemberg, Germany)
|October 23, 2023
概括
三甲基化合物增强了所有固态电池的固体电解质. 在Li6PS5Cl中添加2- ((trimethylsilyl) ethanethiol可以提高与阴极材料的界面稳定性,使2000多个循环能够保持85%的容量.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 电池技术 电池技术
背景情况:
- 由于其高离子导电性和灵活性,基类型Li6PS5Cl (LPSCl) 显示出作为全固态电池 (ASSB) 的固体电解质的前景.
- 然而,LPSCl在电解质-阴极接口处遭受电化学降解,这阻碍了实际应用.
研究的目的:
- 提高ASSB中硫化物基固体电解质和阴极材料之间的界面稳定性.
- 研究使用三甲基化合物作为固体电解质添加剂.
主要方法:
- 引入2- ((trimethylsilyl) 乙乙醇 (TMS-SH) 作为固体电解质添加剂.
- 使用TMS-SH添加剂对Li:LPSCl:LiCoO2细胞进行电化学测试.
- 分析阴极-电解质介相 (CEI) 层的形成.
主要成果:
- 在充电过程中,TMS-SH会氧化分解,形成一个稳定的CEI层.
- 来自TMS-SH的CEI层有效地抑制了LPSCl和LiCoO2.2之间的界面降解.
- 经过修改的固体电解质可实现卓越的电化学性能,达到2000多个周期,容量保持率为85.0%.
结论:
- 三甲基化合物,特别是TMS-SH,是有效的添加剂,可以提高ASSB中硫化物固体电解质的界面稳定性.
- 形成一个稳定的CEI层对于改善ASSB的周期寿命和性能至关重要.
相关概念视频
Preparation and Reactions of Thiols
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Thiols are prepared using the hydrosulfide anion as a nucleophile in a nucleophilic substitution reaction with alkyl halides. For instance, bromobutane reacts with sodium hydrosulfide to give butanethiol.
6.3K
Structure and Nomenclature of Thiols and Sulfides
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Thiols and sulfides are sulfur analogs of alcohols and ethers, respectively, where the sulfur atom takes the place of the oxygen atom. Thus, thiols are generally represented as RSH, where R is an alkyl substituent and —SH is the functional group. On the other hand, in sulfides, the central sulfur atom is bonded to two hydrocarbon groups on either side. Depending upon the type of group, sulfides can be either symmetrical or asymmetrical. Both thiols and sulfides display a bent geometry,...
4.8K
Preparation and Reactions of Sulfides
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Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.
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