在SiO2中封闭的聚乙烯糖醇 - - 改性膨胀石墨作为用于热能存储的新型形式稳定相变材料
Giang Tien Nguyen1, Thi Ai Nhi Truong1, Nguyen Duy Dat1
1Faculty of Chemical and Food Technology, Ho Chi Minh City University of Technology and Education (HCMUTE), 1 Vo Van Ngan, Thu Duc, Ho Chi Minh City 700000, Vietnam.
ACS omega
|October 23, 2023
概括
新的形态稳定相变材料 (FSPCMs) 有效地储存热能. 在SiO2-修饰膨胀石墨 (EG@SiO2) 中封装的聚乙烯甘醇 (PEG) 显示出优异的稳定性和高能储能容量,用于热能储能应用.
科学领域:
- 材料科学 材料科学 材料科学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 变相材料 (PCM) 对于热能储存 (TES) 是至关重要的.
- 开发形式稳定的PCM (FSPCMs) 对于防止泄漏和在相位过渡期间保持结构完整性至关重要.
- 聚乙烯甘醇 (PEG) 是一个有前途的PCM,但其在点以上的液态需要有效的封装.
研究的目的:
- 准备和研究基于聚乙烯糖醇 (PEG) 的新型形态稳定相变材料 (FSPCMs),这些材料被限制在SiO2-修饰扩展石墨 (EG@SiO2) 中.
- 评估开发的FSPCMs的热能存储行为,稳定性和性能.
主要方法:
- 在SiO2修饰的sol-gel方法中,PEG被封装在SiO2修饰的扩展石墨 (EG@SiO2) 中.
- PEG含量在60-90%的重量百分比之间.
- 特性包括表面特性,PEG吸附性,防漏能力,热能存储能力,导热性和循环耐用性.
主要成果:
- 与原始EG相比,EG@SiO2表现出较高的PEG吸附率 (>80重量%) ,确保了有效的封闭.
- 最佳的80%重量的PEG/EG@SiO2复合物表现出高晶度 (93.5%),相当大的热能储能能力 (132.5 J/g) 和优异的热导率 (4.086 W/m·K).
- 在500个化/结晶周期中,FSPCM没有泄漏,并且保持了良好的循环耐用性.
结论:
- 开发的PEG/EG@SiO2 FSPCMs提供了卓越的热稳定性和高储能性能.
- 毛细血管力,表面张力和结合相互作用的组合有效地在多孔网络内固定PEG.
- 这些具有成本效益和高性能的FSPCM适用于大规模的热能存储应用.
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